New Schiff bases based on isatin and (thio)/carbohydrazone: preparation, experimental–theoretical spectroscopic characterization, and DFT approach to antioxidant characteristics
Yazarlar (5)
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
Prof. Dr. Fatih Sönmez Sakarya University Of Applied Sciences, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Belma Z. Kurt
Bezmiâlem Vakıf Üniversitesi, Türkiye
Bezmiâlem Vakıf Üniversitesi, Türkiye
Hasan Yakan Ondokuz Mayis Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Research on Chemical Intermediates (Q2) | ||
| Dergi ISSN | 0922-6168 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2023 |
| Kabul Tarihi | 02-12-2022 | Yayınlanma Tarihi | 21-12-2022 |
| Cilt / Sayı / Sayfa | 49 / 4 / 1463–1484 | DOI | 10.1007/s11164-022-04908-1 |
| Makale Linki | http://dx.doi.org/10.1007/s11164-022-04908-1 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| In this study, synthesis, spectroscopic elucidation, and investigation of antioxidant properties of new Schiff bases based on isatin and (thio)/carbohydrazone derivatives have been reported for the first time. The structures of the synthesized compounds were elucidated by FT-IR, 1H-NMR, and 13C-NMR spectroscopic methods and elemental analysis. Their DPPH, ABTS, and CUPRAC activities were evaluated as antioxidant properties. Electronic and spectral data of the compounds were obtained by DFT calculations at the B3LYP/6–311+ +G(2d,2p) level of theory. Intramolecular interactions and charge densities on the bonds were analyzed by QTAIM and IRI calculations. In addition to parameters such as frontier molecular orbital energy eigenvalues, electronegativity, nucleophilicity index, and electrodonating power, the changes in the enthalpy of the compounds for the reactions realized through the SET … |
| Anahtar Kelimeler |
| Antioxidant assay | DFT | Isatin | Schiff bases | Spectroscopic elucidation |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 12 |
| Scopus | 14 |
| Google Scholar | 16 |