Preparation, antioxidant activity, and theoretical studies on the relationship between antioxidant and electronic properties of bis(thio/carbohydrazone) derivatives
Yazarlar (6)
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
Prof. Dr. Belma Zengin Kurt Bezm-İ Âlem Vakıf Üniversitesi, Türkiye
Prof. Dr. Fatih Sönmez Sakarya Uygulamalı Bilimler Üniversitesi, Türkiye
Prof. Dr. Emre Güzel Sakarya Uygulamalı Bilimler Üniversitesi, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Doç. Dr. Hasan Yakan Ondokuz Mayıs Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Physics and Chemistry of Solids (Q2)
Dergi ISSN 0022-3697 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 05-2022
Kabul Tarihi Yayınlanma Tarihi 01-05-2022
Cilt / Sayı / Sayfa 164 / 1 / 110618–0 DOI 10.1016/j.jpcs.2022.110618
Makale Linki http://dx.doi.org/10.1016/j.jpcs.2022.110618
UAK Araştırma Alanları
Atom, Molekül ve Lazer Fiziği
Özet
A series of novel bis(thio/carbohydrazone) compounds has been prepared from (thio)/carbohydrazide and various aldehyde derivatives. FTIR, 1H and 13C NMR spectroscopy, and elemental analysis have been used to elucidate the structures of synthesized compounds. Their antioxidant properties have been assessed using the DPPH, ABTS, and CUPRAC methods. Most of the synthesized compounds exhibited antioxidant activity in each assay. The effects of the electronic and structural properties of urea/thiourea groups on the antioxidant properties of the compounds have been investigated, and it was observed that thiourea-based compounds showed better antioxidant activity than structurally similar urea-based compounds. Among them, N′,N‴-1,4-phenylene-bis(methaneylylidene)-bis(N′-2-hydroxybenzylidene)methane-bis(thiohydrazide) (9) and N′,N‴-(1,4-phenylene-bis(methaneylylidene)-bis(N′-2,4 …
Anahtar Kelimeler
Antioxidant activity | Carbohydrazones | DFT | Schiff base | Structure elucidation