Phthalocyanines including 2-mercaptobenzimidazole analogs: Synthesis, spectroscopic characteristics, quantum-chemical studies on the relationship between electronic and antioxidant properties
Yazarlar (6)
Doç. Dr. Hasan Yakan Ondokuz Mayis Üniversitesi, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Emre Güzel Sakarya Üniversitesi, Türkiye
Barış S. Arslan
Sakarya Üniversitesi, Türkiye
Sakarya Üniversitesi, Türkiye
Prof. Dr. Temel Kan BAKIR Kastamonu Üniversitesi, Türkiye
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure (Q3) | ||
| Dergi ISSN | 0022-2860 Dergi Bilgileri (2020) | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2020 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-02-2020 |
| Cilt / Sayı / Sayfa | 1202 / 1 / 127259–0 | DOI | 10.1016/j.molstruc.2019.127259 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286019313687 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| In this study, peripherally tetra 2-mercaptobenzimidazole group substituted cobalt and indium phthalocyanine complexes (2 and 3) were prepared from 4-(benzo[d]imidazole-2-ylthio)phthalonitrile (1) for the first time. Antioxidant behaviors and theoretical calculations of benzimidazole-substituted metallophthalocyanines are presented. The structures of these compounds were determined by the spectroscopic methods (IR, 1H NMR, UV–Vis and mass spectroscopies) and elemental analysis. Antioxidant activities of the compounds (1–3) were measured using 1,1-diphenyl-2-picrylhydrazyl (DPPH) method. Antioxidant activity was followed by 1 > 3 > 2 > Trolox. In addition, density functional theory (DFT) calculations were carried out to determine the stable electronic structure, charge density distributions, FMO energy eigenvalues, and electronegativity of the ligand (1) and complexes (2 and 3). NBO and QTAIM … |
| Anahtar Kelimeler |
| Antioxidant activity | DFT | Phthalocyanine | QTAIM | Spectroscopic methods |
Science Direct
Phthalocyanines including 2-mercaptobenzimidazole analogs: Synthesis, spectroscopic characteristics, quantum-chemical studies on the relationship between electronic and antioxidant properties
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 14 |
| Scopus | 14 |
| Google Scholar | 16 |