New β-isatin aldehyde-N,N′-thiocarbohydrazones: preparation, spectroscopic studies and DFT approach to antioxidant characteristics
Yazarlar (4)
Doç. Dr. Hasan Yakan Ondokuz Mayıs Üniversitesi, Türkiye
Prof. Dr. Temel Kan BAKIR Kastamonu Üniversitesi, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Research on Chemical Intermediates (Q2) | ||
| Dergi ISSN | 0922-6168 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2020 |
| Kabul Tarihi | 05-09-2020 | Yayınlanma Tarihi | 17-09-2020 |
| Cilt / Sayı / Sayfa | 46 / 12 / 5417–5440 | DOI | 10.1007/s11164-020-04270-0 |
| Makale Linki | http://link.springer.com/10.1007/s11164-020-04270-0 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| Five new Schiff bases of isatin and its derivatives were prepared from monothiocarbohydrazides and 5-chloro isatin. The chemical structures of the synthesized compounds were performed by 1H NMR, 13C NMR, and FT-IR spectroscopic techniques and elemental analysis. The in vitro antioxidant activities of all the products were determined by 1,1-Diphenyl-2-Picryl Hydrazyl free radical scavenging method. It also examined the antioxidant properties of the compounds based on quantum chemical calculations as well as supporting experimental spectroscopic data. Theoretical calculations carried out at B3LYP correlation functional with 6-311++g(2d,2p) basis set. Some chemical reactivity descriptors obtained from AIM, NCI, and ELF analysis were used to reveal the relationship between the electronic and antioxidant properties of the compounds. Furthermore, the bond lengths, charge densities, potential energy … |
| Anahtar Kelimeler |
| AIM | Antioxidant assay | ELF analysis | NCI | Schiff bases | Spectroscopic techniques |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 33 |
| Scopus | 35 |
| Google Scholar | 38 |