New amide based iridium( scpiii/scp ) complexes: synthesis, characterization, photoluminescence and DFT/TD-DFT studies/title
Yazarlar (4)
Prof. Dr. Çiğdem Şahin Pamukkale Üniversitesi, Türkiye
Aysen Gören
Pamukkale Üniversitesi, Türkiye
Pamukkale Üniversitesi, Türkiye
Prof. Dr. Serkan Demir Giresun Üniversitesi, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | New Journal of Chemistry (Q2) | ||
| Dergi ISSN | 1144-0546 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2018 |
| Cilt / Sayı / Sayfa | 42 / 4 / 2979–2988 | DOI | 10.1039/c7nj04671e |
| Makale Linki | http://xlink.rsc.org/?DOI=C7NJ04671E | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| New iridium(III) complexes with 2-(3-fluorophenyl)-4-methylpyridine as cyclometalated ligands and 2,2′-bipyridine-4,4′-dicarboxamide derivatives as ancillary ligands were synthesized and characterized by FTIR, NMR, MS, UV/Visible, and fluorescence spectroscopies and cyclic voltammetry. The effects of different solvents and substituents on the photophysical properties of the complexes have been investigated. The complexes show tunable photoluminescence wavelengths depending on solvent polarity in the 548 nm to 610 nm range where the emission colour can change from green to orange-red. The complexes exhibit high photoluminescence quantum yields between 0.41 and 0.75, which may be attributed to the change in the transition dipole moment originating from the amide group upon electronic excitation. The calculated HOMO and LUMO energy levels of complexes 1–7 are in the −5.51 to −5.60 eV … |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 14 |
| Scopus | 14 |
| Google Scholar | 15 |