Synthesis, Structural Characterization AndTheoretical Investigations of New Azo-Azomethine Compounds Bearing Acryloyl Moiety
Yazarlar (3)
Prof. Dr. Sevil Özkınalı Hitit Üniversitesi, Türkiye
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Büşra Sakin
| Makale Türü |
Özgün Makale
(Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayınlanan tam makale)
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| Dergi Adı | Hittite Journal of Science Engineering | ||
| Dergi ISSN | 2149-2123 | ||
| Dergi Tarandığı Indeksler | TR DİZİN | ||
| Makale Dili | İngilizce | Basım Tarihi | 12-2018 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-01-2018 |
| Cilt / Sayı / Sayfa | 5 / 4 / 259–269 | DOI | 10.17350/HJSE19030000101 |
| Makale Linki | https://www.hjse.hitit.edu.tr/hjse/index.php/HJSE/article/view/HJSE19030000101 | ||
| UAK Araştırma Alanları |
Atom, Molekül ve Lazer Fiziği
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| Özet |
| I n this study six new azo-azomethine dyes containing acryloyl group, 4-[[[4-[4′-methyl phenyl azo phenyl] imino] methyl] phenyl-2-propenoat, 4-[[[4-[4′- hydroxy phenylazo phenyl] imino] methyl] phenyl-2-propenoat, 4-[[[4- phenyl azo phenyl] imino] methyl]- phenyl-2-propenoat, 4-[[[4-[4′-chloro phenyl azo phenyl] imino] methyl] phenyl-2-propenoat, 4-[[[4-[4′- nitro phenyl azo phenyl] imino] methyl] phenyl-2propenoat were synthesized. The acryloyl derivatives of the azo-azomethine dyes were prepared with metallic sodium and acryloyl chloride in 1:1 Molar ratio and characterized using elemental analysis, IR, UV-Vis, 1H-NMR and 13C-NMR spectroscopy. The molecular geometry was also optimized using density functional theory DFT/B3LYP method with the 6-311G 2d,2p and cc-pvtz basis sets in ground state. From the optimized geometry of the compounds, vibrational frequencies, UV-Vis, molecular electrostatic potential distribution and frontier molecular orbitals were performed using same method and basis stets, and the results were compared with the experimental data |
| Anahtar Kelimeler |
BM Sürdürülebilir Kalkınma Amaçları
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| Google Scholar | 3 |