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Synthesis and characterization of fully aromatic thermotropic liquid crystalline copolyesters containingm hydroxybenzoic acid units     
Yazarlar (3)
Prof. Dr. Zekeriya YERLİKAYA Prof. Dr. Zekeriya YERLİKAYA
Gazi Üniversitesi, Türkiye
Serpil Aksoy
Bayramlı Erdal
Devamını Göster
Özet
A series of fully aromatic copolyesters based on p‐acetoxybenzoic acid (p‐ABA), hydroquinone diacetate (HQDA), terephthalic acid (TPA), and m‐acetoxybenzoic acid (m‐ABA) were prepared by a modified melt‐polycondensation reaction. The copolyesters were characterized by DSC, thermogravimetric analysis, 1H NMR, polarized optical microscopy, X‐ray diffraction, and intrinsic viscosity measurements. The copolyesters exhibited nematic liquid‐crystalline phases in a broad temperature range of about 150 °C, when the content of linear (p‐ABA, HQDA, and TPA) units was over 67 mol %. DSC analysis of the anisotropic copolyesters revealed broad endotherms associated with the nematic phases, and the melting or flow temperatures were found to be in the processable region. The flow temperatures and crystal‐to‐nematic and nematic‐to‐isotropic transitions depend on the type of linear monomer units, and …
Anahtar Kelimeler
aromatic | liquid-crystalline polymer | copolymerization | polyesters | thermal properties | degree of crystallinity | sequence distribution
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Dergi ISSN 0887-624X Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 10-2001
Cilt No 39
Sayı 19
Sayfalar 3263 / 3277
Doi Numarası 10.1002/pola.1309
Makale Linki http://doi.wiley.com/10.1002/pola.1309