Yazarlar |
Tuncer Çaykara
Gazi Üniversitesi, Türkiye |
Prof. Dr. Zekeriya YERLİKAYA
Gazi Üniversitesi, Türkiye |
Kantoğlu Ömer
|
Özet |
Poly(2-hydroxyethyl methacrylate-crotonic acid) P(HEMA/CrA) copolymers with varying compositions were prepared from ternary mixtures of 2-hydroxyethyl methacrylate (HEMA)/crotonic acid (CrA)/water by using 60Co γ-rays. The wetting forces were determined according to the Wilhelmy Plate Technique. Di-iodomethane, ethylene glycol, and formamide were used as probe liquids. Lifshitz-van der Waals surface energy components, Lewis acid-base surface components, and total surface energies were calculated using van Oss et al. methodology. It was determined that Lifshitz-van der-Waals component (γSLW) of the copolymers did not differ much from the copolymer composition. However, the electron-donor surface free energy components (γS-) of the copolymers were decreased considerably with the increase of the CrA content of the copolymers, the surfaces of these copolymers were still found to have a basic character. |
Anahtar Kelimeler |
Poly(2-hydroxyethyl methacrylate-crotonic acid) | Surface free energy | Wettability |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY |
Dergi ISSN | 1060-1325 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 01-2003 |
Cilt No | 40 |
Sayı | 11 |
Sayfalar | 1173 / 1182 |
Doi Numarası | 10.1081/MA-120024832 |
Makale Linki | http://www.tandfonline.com/doi/abs/10.1081/MA-120024832 |