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The Effect of Copolymer Composition on Surface Free Energy of Poly 2 Hydroxyethyl Methacrylate Crotonic Acid Copolymers      
Yazarlar (3)
Tuncer Çaykara
Gazi Üniversitesi, Türkiye
Prof. Dr. Zekeriya YERLİKAYA Prof. Dr. Zekeriya YERLİKAYA
Kastamonu Üniversitesi, Türkiye
Ömer Kantoglu
Tenmak (Turkish Energy, Nuclear And Mineral Research Agency), Türkiye
Devamını Göster
Özet
Poly(2-hydroxyethyl methacrylate-crotonic acid) P(HEMA/CrA) copolymers with varying compositions were prepared from ternary mixtures of 2-hydroxyethyl methacrylate (HEMA)/crotonic acid (CrA)/water by using 60Co γ-rays. The wetting forces were determined according to the Wilhelmy Plate Technique. Di-iodomethane, ethylene glycol, and formamide were used as probe liquids. Lifshitz-van der Waals surface energy components, Lewis acid-base surface components, and total surface energies were calculated using van Oss et al. methodology. It was determined that Lifshitz-van der-Waals component (γSLW) of the copolymers did not differ much from the copolymer composition. However, the electron-donor surface free energy components (γS-) of the copolymers were decreased considerably with the increase of the CrA content of the copolymers, the surfaces of these copolymers were still found to have a basic character.
Anahtar Kelimeler
Poly(2-hydroxyethyl methacrylate-crotonic acid) | Surface free energy | Wettability
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale
Dergi Adı Journal of Macromolecular Science Pure and Applied Chemistry
Dergi ISSN 1060-1325 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce
Basım Tarihi 01-2003
Cilt No 40
Sayı 11
Sayfalar 1173 / 1182
Doi Numarası 10.1081/MA-120024832
Makale Linki http://www.tandfonline.com/doi/abs/10.1081/MA-120024832