Surface free energy analysis of poly N vinyl 2 pyrrolidone crotonic acid copolymers prepared by Gamma ray induced polymerization technique
Yazarlar (3)
Tuncer Caykara
Gazi Üniversitesi, Türkiye
Prof. Dr. Zekeriya YERLİKAYA Kastamonu Üniversitesi, Türkiye
Omer Kantoglu
Tenmak (Turkish Energy, Nuclear And Mineral Research Agency), Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Applied Polymer Science
Dergi ISSN 0021-8995 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 02-2004
Kabul Tarihi Yayınlanma Tarihi 05-12-2003
Cilt / Sayı / Sayfa 91 / 3 / 1893–1897 DOI 10.1002/app.13245
Makale Linki http://doi.wiley.com/10.1002/app.13245
UAK Araştırma Alanları
Polimer Bilimi
Özet
Pure poly (N-vinyl-2-pyrrolidone)(PVP) and P (VP–crotonic acid)[P (VP/CrA)] copolymers with different CrA contents were prepared by the-ray-induced polymerization technique. The change in the surface free energy of the copolymers was investigated using the Van Oss–Good contact angle evaluation methodology in order to estimate their wettability properties. The apolar Lifshitz–van der Waals component (S LW) and the electron donor component (S) of the PVP network were calculated as 27.6 and 56.5 mN m 1, respectively. In this case, the surface of the PVP network had a basic character (electron donor). By contrast, the S LW component of P (VP/CrA) copolymers increased and then remained almost constant with increasing CrA content. In addition, the surface of these copolymers changed from a basic character (S 56.5 mN m 1) to an acidic character (S 0.07 mN m 1) with increasing CrA contents in the …
Anahtar Kelimeler
Networks | Poly(N-vinyl-2-pyrrolidone-crotonic acid) | Radiation | Surfaces