Yazarlar |
Tuncer Çaykara
Gazi Üniversitesi, Türkiye |
Prof. Dr. Zekeriya YERLİKAYA
Gazi Üniversitesi, Türkiye |
Kantoğlu Ömer
|
Özet |
Pure poly(N-vinyl-2-pyrrolidone) (PVP) and P(VP-crotonic acid) [P(VP/CrA)] copolymers with different CrA contents were prepared by the γ-ray-induced polymerization technique. The change in the surface free energy of the copolymers was investigated using the Van Oss-Good contact angle evaluation methodology in order to estimate their wettability properties. The apolar Lifshitz-van der Waals component (γSLW) and the electron donor component (γs-) of the PVP network were calculated as 27.6 and 56.5 mN m-1, respectively. In this case, the surface of the PVP network had a basic character (electron donor). By contrast, the γSLW component of P(VP/CrA) copolymers increased and then remained almost constant with increasing CrA content. In addition, the surface of these copolymers changed from a basic character (γS- = 56.5 mN m-1) to an acidic character (γS+ = 0.07 mN m-1) with increasing CrA contents in the copolymer. |
Anahtar Kelimeler |
Networks | Poly(N-vinyl-2-pyrrolidone-crotonic acid) | Radiation | Surfaces |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | JOURNAL OF APPLIED POLYMER SCIENCE |
Dergi ISSN | 0021-8995 |
Dergi Tarandığı Indeksler | SCI |
Makale Dili | İngilizce |
Basım Tarihi | 02-2004 |
Cilt No | 91 |
Sayı | 3 |
Sayfalar | 1893 / 1897 |
Doi Numarası | 10.1002/app.13245 |
Makale Linki | http://doi.wiley.com/10.1002/app.13245 |