Thermal Properties and Crystallinity of Thermotropic Liquid Crystalline Copolyesters Prepared from Poly ethylene terephtalate PET and Rigid Aromatic Units
Yazarlar (4)
Abdullah Tan
Kirikkale Üniversitesi, Türkiye
Doç. Dr. Haydar Altınok Kırıkkale Üniversitesi, Türkiye
Prof. Dr. Zekeriya YERLİKAYA Kastamonu Üniversitesi, Türkiye
Serpil Aksoy
Gazi Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Journal of Macromolecular Science Part A Pure and Applied Chemistry
Dergi ISSN 1060-1325 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 04-2007
Kabul Tarihi Yayınlanma Tarihi 01-04-2007
Cilt / Sayı / Sayfa 44 / 4 / 425–431 DOI 10.1080/10601320601188323
Makale Linki http://www.tandfonline.com/doi/abs/10.1080/10601320601188323
UAK Araştırma Alanları
Polimer Bilimi
Özet
A series of copolyesters were synthesized by melt‐polycondensation reaction of poly(ethylene terephtalate) (PET) with various proportions of equimolar compositions of p‐acetoxybenzoic acid (p‐ABA), hydroquinone diacetate (HQDA) and terephtalic acid (TPA). Viscosity, liquid crystallinity, thermal properties, degree of crystallinity and thermal stabilitiy of these copolyesters were investigated by Ubbelohde viscometer, hot‐stage polarized light microscopy (PLM), differential scanning calorimetry (DSC), wide‐angle X‐ray diffraction (WAXD) and thermogravimetric analysis (TGA), respectively. On the basis of viscosity measurement, it was observed that intrinsic viscosity values of the copolyesters are increased regularly with increasing amounts of aromatic units (p‐ABA, HQDA and TPA) in the polymer chain. Thermotropic liquid crystalline behavior was observed in the copolyesters containing over 50 mol% of rigid p …
Anahtar Kelimeler
Copolymerization | Crystallinity | Liquid-crystalline copolyester | Poly(ethylene terephthalate) | Thermal properties