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Synthesis and Crystal Structure of 3-Amino-1-(5-Chloro-2-Hydroxyphenyl)Imidazolidine-2,4-Dione      
Yazarlar
Prof. Dr. Abdullah AYDIN Prof. Dr. Abdullah AYDIN
Kastamonu Üniversitesi, Türkiye
Tijen Önkol
Türkiye
Mehmet Akkurt
Erciyes Üniversitesi, Türkiye
Orhan Büyükgüngör
Türkiye
Mustafa Fethi Şahin
Türkiye
Özet
The present study describes the synthesis, spectral data, and single crystal X-ray structural analysis of 3-amino-1-(5-chloro-2-hydroxyphenyl) imidazolidine-2,4-dione. X-Ray analysis revealed that the title compound did not have the anticipated structure, but had that of a different substance. This unexpected conformation generated the interest in studying the synthesis of this compound. The inspected compound, 3-amino-1-(5-chloro-2-hydroxyphenyl) imidazolidine-2,4-dione, is a pharmaceutical intermediate and is nonplanar. Its benzene and five-membered rings have a dihedral angle of 53.95(7)°. The conformation is stabilized by intermolecular OH. O, OH. N, and NH. O interactions and a weak CH. π interaction. © 2013 Copyright Taylor and Francis Group, LLC.
Anahtar Kelimeler
3-amino | 4-dione | structure | synthesis | X-ray
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı MOLECULAR CRYSTALS AND LIQUID CRYSTALS
Dergi ISSN 1542-1406
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 01-2013
Cilt No 570
Sayı 1
Sayfalar 119 / 127
Doi Numarası 10.1080/15421406.2012.707593
Makale Linki http://dx.doi.org/10.1080/15421406.2012.707593
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Synthesis and Crystal Structure of 3-Amino-1-(5-Chloro-2-Hydroxyphenyl)Imidazolidine-2,4-Dione

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