Yazarlar |
Prof. Dr. Abdullah AYDIN
Kastamonu Üniversitesi, Türkiye |
Tijen Önkol
Türkiye |
Mehmet Akkurt
Erciyes Üniversitesi, Türkiye |
Orhan Büyükgüngör
Türkiye |
Mustafa Fethi Şahin
Türkiye |
Özet |
The present study describes the synthesis, spectral data, and single crystal X-ray structural analysis of 3-amino-1-(5-chloro-2-hydroxyphenyl) imidazolidine-2,4-dione. X-Ray analysis revealed that the title compound did not have the anticipated structure, but had that of a different substance. This unexpected conformation generated the interest in studying the synthesis of this compound. The inspected compound, 3-amino-1-(5-chloro-2-hydroxyphenyl) imidazolidine-2,4-dione, is a pharmaceutical intermediate and is nonplanar. Its benzene and five-membered rings have a dihedral angle of 53.95(7)°. The conformation is stabilized by intermolecular OH. O, OH. N, and NH. O interactions and a weak CH. π interaction. © 2013 Copyright Taylor and Francis Group, LLC. |
Anahtar Kelimeler |
3-amino | 4-dione | structure | synthesis | X-ray |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | MOLECULAR CRYSTALS AND LIQUID CRYSTALS |
Dergi ISSN | 1542-1406 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Dergi Grubu | Q4 |
Makale Dili | İngilizce |
Basım Tarihi | 01-2013 |
Cilt No | 570 |
Sayı | 1 |
Sayfalar | 119 / 127 |
Doi Numarası | 10.1080/15421406.2012.707593 |
Makale Linki | http://dx.doi.org/10.1080/15421406.2012.707593 |