A Novel Ferrocenyl Naphthoquinone Fused Crown Ether as a Multisensor for Water Determination in Acetonitrile and Selective Cation Binding
Yazarlar (4)
Öğr. Gör. Dr. Metin DAĞDEVİREN Kastamonu Üniversitesi, Türkiye
Prof. Dr. İsmail Yılmaz İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Barış Yücel İstanbul Teknik Üniversitesi, Türkiye
Doç. Dr. Mustafa Emirik Recep Tayyip Erdogan University, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Physical Chemistry B | ||
| Dergi ISSN | 1520-6106 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 01-2015 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 09-09-2015 |
| Cilt / Sayı / Sayfa | 119 / 38 / 12464–12479 | DOI | 10.1021/acs.jpcb.5b06590 |
| Makale Linki | http://dx.doi.org/10.1021/acs.jpcb.5b06590 | ||
| UAK Araştırma Alanları |
Analitik Kimya
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| Özet |
| A multisensor which is based on a novel multifunctional triad molecule, ferrocenyl naphthoquinone fused crown ether (Fc–cnq) bearing ferrocene, quinone, and crown ether functional groups together, was synthesized and characterized in this study. Sensing performance of a trace amount of water and the selective cation binding capabilities of this multisensor were carried out by the electrochemical, spectroelectrochemical, and spectrophotometric titration techniques in acetonitrile (CH3CN). It was shown that the potential separation (E(Fc)1/2 – E(2)1/2) between the second reduction of naphthoquinone and the oxidation processes of ferrocene in the triad molecule Fc–cnq was proportional to the amount of water due to the hydrogen-bonding interactions between water and the doubly reduced species (Fc–cnq2–). This property enabled Fc–cnq to detect the trace amount of water in CH3CN. The half-wave potential … |
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| Atıf Sayıları | |
| Web of Science | 16 |
| Scopus | 16 |
| Google Scholar | 19 |