Synthesis and characterization of solution processable 6,11-dialkynyl substituted indeno[1,2-b]anthracenes
Yazarlar (7)
Prof. Dr. Barış Yücel İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Duygu Ekinci Atatürk Üniversitesi, Türkiye
Prof. Dr. Nurcan Tüzün Atatürk Üniversitesi, Türkiye
Süheyla Özbey Tübitak Ulusal Metroloji Enstitüsü, Türkiye
Canan Kazak İstanbul Teknik Üniversitesi, Türkiye
Öğr. Gör. Gülru Kayık Hacettepe Üniversitesi, Türkiye
Öğr. Gör. Dr. Metin DAĞDEVİREN Kastamonu Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Dyes and Pigments (Q1)
Dergi ISSN 0143-7208 Dergi Bilgileri (2014)
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 01-2014
Kabul Tarihi Yayınlanma Tarihi 01-01-2014
Cilt / Sayı / Sayfa 100 / 1 / 250–250 DOI 10.1016/j.dyepig.2013.08.024
Makale Linki http://dx.doi.org/10.1016/j.dyepig.2013.08.024
UAK Araştırma Alanları
Organik Kimya
Özet
Twelve indene-fused dialkynyl substituted anthracene derivatives (indenoanthracenes) were synthesized and their optical, electrochemical and thermal properties were described. These small molecules possess high quantum yields, thermal and photoxidative stabilities, and solubility in common organic solvents. Indenoanthracenes (57–92%) were prepared in two steps from four different indenoanthraquinones obtained via a highly selective and practical benzocyclobutendione based methodology. The photophysical properties of indenoanthracenes were investigated by UV–vis and fluorescence spectroscopies. From spectroscopic data of indenoanthracenes, quantum yields (Φƒ, 0.28–0.71) and optical HOMO–LUMO energy gaps were determined. Electrochemistry of indenoanthracenes was studied and electrochemical HOMO–LUMO energy gaps were also determined from the onset oxidation and reduction …
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