Ketone synthesized cobaloxime/organocobaloxime catalysts for cyclic carbonate synthesis from CO2 and epoxides: Characterization and electrochemistry
Yazarlar (6)
Prof. Dr. Ahmet Kılıç Harran Üniversitesi, Türkiye
Mahmut Ulusoy
Harran Üniversitesi, Türkiye
Harran Üniversitesi, Türkiye
Prof. Dr. Mustafa Durgun Harran Üniversitesi, Türkiye
Doç. Dr. Emine Aytar Harran Üniversitesi, Türkiye
Öğr. Gör. Dr. Metin DAĞDEVİREN Kastamonu Üniversitesi, Türkiye
Prof. Dr. İsmail Yılmaz İstanbul Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Organometallic Chemistry | ||
| Dergi ISSN | 0022-328X Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 01-2014 |
| Kabul Tarihi | – | Yayınlanma Tarihi | 01-09-2014 |
| Cilt / Sayı / Sayfa | 767 / 1 / 150–159 | DOI | 10.1016/j.jorganchem.2014.05.023 |
| Makale Linki | http://dx.doi.org/10.1016/j.jorganchem.2014.05.023 | ||
| UAK Araştırma Alanları |
Analitik Kimya
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| Özet |
| Herein we report the synthesis and characterization of a new series of synthesized mono- and trinuclear cobaloxime/organocobaloximes from ketone that act as catalysts for cyclic carbonate synthesis from CO2 and epoxides under appropriate conditions (2 h, 100 °C and 1.6 MPa pressure). These reactions were carried out with and without co-catalyst, namely, 4-dimethylaminopyridine (DMAP), pyridine (py), triethyl amine (NEt3) or triphenyl phosphine (PPh3). In the catalytic experiments, the 4-dimethylaminopyridine (DMAP) was used as co-catalyst, since the DMAP was a more active base with higher yield compared to other Lewis bases. In addition, various factors influencing the cycloaddition reaction, such as co-catalyst, temperature, CO2 pressure and reaction time, were investigated. A dioxime ligand (LH2) (1) was obtained in two steps from 4-methylpropiophenone as ketone. Reaction of CoCl2.6H2O with the … |
| Anahtar Kelimeler |
| Carbon dioxide | Cobaloxime | Cyclic carbonate | Electrochemistry | Spectroscopy |
Science Direct
Ketone synthesized cobaloxime/organocobaloxime catalysts for cyclic carbonate synthesis from CO2 and epoxides: Characterization and electrochemistry
| Atıf Sayıları | |
| Web of Science | 32 |
| Scopus | 33 |
| Google Scholar | 45 |