| Yazarlar |
Ahmet Kılıç
Türkiye |
|
Ahmet Arif Palalı
Türkiye |
|
Mustafa Durgun
Türkiye |
|
Zeynep Taşcı
Türkiye |
|
Mahmut Ulusoy
Türkiye |
Öğr. Gör. Dr. Metin DAĞDEVİREN
Kastamonu Üniversitesi, Türkiye |
|
İsmail Yılmaz
Türkiye |
| Özet |
| Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by 1H and 13C NMR spectra, FT-IR, UV-Vis, elemental analysis, melting point measurements, LC-MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)2] complex (2). Then, the intramolecular O-H⋯O bridges are replaced with Cu(II)(N-N) complex to synthesize multinuclear [Ni(dioxime)2Cu2(N-N) 2](ClO4)2 oxime complexes (3-7) where N-N = 2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2, 2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime) 2] (2) was used as a precursor for building multinuclear oxime complexes (3-7). In this paper, our goal is to study spectroscopic, electrochemical and catalytic properties of this new ligand and its metal complexes. © 2012 Elsevier B.V. All rights reserved. |
| Anahtar Kelimeler |
| Oxime complexes,Mass spectra,Electrochemistry,Carbon dioxide,Cyclic carbonate |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Inorganica Chimica Acta |
| Dergi ISSN | 0020-1693 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | Türkçe |
| Basım Tarihi | 01-2013 |
| Cilt No | 394 |
| Doi Numarası | 10.1016/j.ica.2012.09.020 |
| Makale Linki | http://dx.doi.org/10.1016/j.ica.2012.09.020 |
