Synthesis, characterization, electrochemical properties and conversions of carbon dioxide to cyclic carbonates mononuclear and multinuclear oxime complexes using as catalyst
Yazarlar (7)
Prof. Dr. Ahmet Kılıç Harran Üniversitesi, Türkiye
Ahmet Arif Palalı
Harran Üniversitesi, Türkiye
Prof. Dr. Mustafa Durgun Harran Üniversitesi, Türkiye
Zeynep Taşcı
Muğla Sıtkı Koçman Üniversitesi, Türkiye
Mahmut Ulusoy
Harran Üniversitesi, Türkiye
Öğr. Gör. Dr. Metin DAĞDEVİREN Kastamonu Üniversitesi, Türkiye
Prof. Dr. İsmail Yılmaz İstanbul Teknik Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Inorganica Chimica Acta
Dergi ISSN 0020-1693 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 01-2013
Kabul Tarihi Yayınlanma Tarihi 01-01-2013
Cilt / Sayı / Sayfa 394 / 1 / 635–644 DOI 10.1016/j.ica.2012.09.020
Makale Linki http://dx.doi.org/10.1016/j.ica.2012.09.020
UAK Araştırma Alanları
Analitik Kimya
Özet
Unsymmetrical dioxime ligand and its mono- and multinuclear metal complexes were synthesized and characterized by 1H and 13C NMR spectra, FT-IR, UV–Vis, elemental analysis, melting point measurements, LC–MS spectroscopy, molar conductivity measurements and magnetic susceptibility and cyclic voltammetry techniques. We firstly prepared new unsymmetrical dioxime ligand (1) and its mononuclear [Ni(dioxime)2] complex (2). Then, the intramolecular O−H⋯O bridges are replaced with Cu(II)(N–N) complex to synthesize multinuclear [Ni(dioxime)2Cu2(N–N)2](ClO4)2 oxime complexes (3–7) where N–N=2,2′-bipyridine (bpy), 1,10-phenanthroline (phen), 3,3′-dicarboxy-2,2′-bipyridine (dcbpy), 4,5-diazafluoren-9-one (dafo) and 1,10-phenanthroline-5,6-dione (dione). The mononuclear complex [Ni(dioxime)2] (2) was used as a precursor for building multinuclear oxime complexes (3–7). In this paper, our …
Anahtar Kelimeler
Carbon dioxide | Cyclic carbonate | Electrochemistry | Mass spectra | Oxime complexes