Monitoring the Degradation of 4-Sulfonyldipenyl-Pyromellitic Dianhy-dride-Based Polyamic Acid by Trametes Versicolor
Yazarlar (1)
Prof. Dr. İdris YAZGAN Kastamonu Üniversitesi, Türkiye
Makale Türü Açık Erişim Özgün Makale (Ulusal alan endekslerinde (TR Dizin, ULAKBİM) yayınlanan tam makale)
Dergi Adı Celal Bayar Üniversitesi Fen Bilimleri Dergisi
Dergi ISSN 1305-130X
Dergi Tarandığı Indeksler TR DİZİN
Makale Dili Türkçe Basım Tarihi 03-2019
Kabul Tarihi 08-02-2019 Yayınlanma Tarihi 22-03-2019
Cilt / Sayı / Sayfa 15 / 1 / 65–69 DOI 10.18466/cbayarfbe.459381
Makale Linki http://dergipark.gov.tr/doi/10.18466/cbayarfbe.459381
UAK Araştırma Alanları
Biyokimya
Özet
Polyamic acid (PAA) polymers have been utilized over 60 years in industry as precursors of polyimide, andcurrently direct utilization of PAA polymers have got great attention for material science applications. Massutilization of synthetic polymers pose threat to living organisms and nature, so their effective degradationis important. In this study, for the first time, degradation of 4-sulfonyldipenyl-pyromellitic dianhydridebased PAA (DSPAA) polymers were performed in batch bioreactor system. 1 H COSY NMR was utilized toenlight the possible mechanism behind Tramates versicolor mediated degradation of DSPAA polymer.Elimination of aromatic peaks belong to DSPAA polymer and its amine monomer were monitored toevaluate the degradation while formation of new peaks was taken into account to propose possibledegradation pathway. NMR studies revealed that 20-day incubation in the designed media is enough tototally eliminate 1 mg/mL DSPAA. The findings can contribute to the knowledge of fungi mediatedaromatic polymer degradation, which is accepted a promising way to eliminate polymer pollution.
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