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Synthesis and Characterization of Novel Chiral (1R,2R)-1,2-Bis[5-(Aminomethylphospinic Acid)-1,3,4-Thiadiazol-2-YL]Ethane-1,2-Diols       
Yazarlar (4)
Pelin Koparır
Muhsin Karaarslan
Aksaray Üniversitesi, Türkiye
Öğr. Gör. Dr. Cahit ÖREK Öğr. Gör. Dr. Cahit ÖREK
Kastamonu Üniversitesi, Türkiye
Metin Koparır
Fırat Üniversitesi, Türkiye
Devamını Göster
Özet
(1R,2R)-1,2-bis[5-(arylideneamino)-1,3,4-thiadiazol-2-yl]ethane-1,2-diol (2a-d) were synthesized by using appropriate aldehydes and (1R,2R)-1,2-bis(5- amino-1,3,4-thiadiazol-2-yl)ethane-1,2-diol (1) as a starting compound. Then, the phosphinic acid component (3a-d) were obtained from (2a-d) and hypophosporus acid. In addition, the structures of the novel chiral compounds (2a-d) and (3a-d) were confirmed by elemental analyses, IR, 1H-NMR, 13C-NMR, and 31P-NMR spectra. 1H NMR and 13C NMR spectra for 1, 2a, and 3a (Figures S1-S6) are available online in the Supplemental Materials. Copyright © Taylor and Francis Group, LLC 2012.
Anahtar Kelimeler
1,3,4-Thiadiazole | aminophosphinic acid | ethane-1,2-diol | tartaric acid
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Dergi ISSN 1042-6507
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili İngilizce
Basım Tarihi 01-2012
Cilt No 187
Sayı 7
Sayfalar 864 / 870
Doi Numarası 10.1080/10426507.2011.636412
Makale Linki http://dx.doi.org/10.1080/10426507.2011.636412