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Decolorization of reactive azo dye by fenton and photo-fenton processes in aqueous solution: The influence of operating conditions, kinetics study, and performance comparison     
Yazarlar
Dr. Öğr. Üyesi Gökçe Didar DEĞERMENCİ Dr. Öğr. Üyesi Gökçe Didar DEĞERMENCİ
Kastamonu Üniversitesi, Türkiye
Özet
In this study, the effect of Fenton and photo-Fenton processes, which are advanced oxidation processes that use the hydroxyl radical for the decolorization of Novacron Black from aqueous solutions, on decolorization was investigated. Optimum levels of initial pH, temperature, hydrogen peroxide concentration, initial dyestuff concentration, and iron concentration were determined. Initial pH, Fe2+ concentration, temperature, and initial Novacron Black concentration are the most effective experimental parameters in the decolorization of Novacron Black with Fenton and photo-Fenton processes. While the Novacron Black concentration was 200 mg/L, the H2O2 concentration was 100 mg/L, the initial solution pH was 3, and the temperature was 20 °C, a decolorization efficiency of 82.1% was obtained in the Fenton process at a concentration of 5 mg/L Fe2+, while in the photo-Fenton process at a 2 mg/L Fe2+ concentration, a 94.6% decolorization efficiency was obtained. Upon decolorization of Novacron Black, the photo-Fenton process had a higher removal efficiency than the Fenton process, even at low iron concentrations. From data obtained at various concentrations of initial Novacron Black, the non-linear method was used to determine the decolorization kinetics of Novacron Black. Finally, an economic analysis was carried out to compare the differences in operating costs between Fenton and photo-Fenton processes.
Anahtar Kelimeler
Advanced oxidation process | Decolorization | Fenton oxidation | Kinetic model | Photo-Fenton oxidation
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı BULLETIN OF THE CHEMICAL SOCIETY OF ETHIOPIA
Dergi ISSN 1011-3924
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q3
Makale Dili İngilizce
Basım Tarihi 03-2023
Cilt No 37
Sayı 1
Sayfalar 197 / 210
Doi Numarası 10.4314/bcse.v37i1.16
Makale Linki http://dx.doi.org/10.4314/bcse.v37i1.16