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Kinetics and mechanism of removal of methylene blue by adsorption onto perlite       
Yazarlar
Mehmet Doğan
Balıkesir Üniversitesi, Türkiye
Mahir Alkan
Balıkesir Üniversitesi, Türkiye
Doç. Dr. Aydın TÜRKYILMAZ Doç. Dr. Aydın TÜRKYILMAZ
Kastamonu Üniversitesi, Türkiye
Yasemin Turhan
Balıkesir Üniversitesi, Türkiye
Özet
The kinetics and mechanism of methylene blue adsorption on perlite have been studied. The effects of various experimental parameters, such as initial dye concentration, temperature and pH on the adsorption rate were investigated. Adsorption measurements show that the process is very fast and physical in nature. The extent of the dye removal increased with increase in the initial concentration of the dye and the initial pH and temperature of solution. Adsorption data were modelled using the first and second-order kinetic equations, mass transfer and intra-particle diffusion models. It was shown that the second-order kinetic equation could best describe the sorption kinetics. The diffusion coefficient, D, was found to increase when the initial dye concentration, pH and temperature were raised. Thermodynamic activation parameters, such as ΔG*, ΔS* and ΔH*, were calculated. © 2004 Elsevier B.V. All rights reserved.
Anahtar Kelimeler
Dye | Intra-particle diffusion | Kinetics of adsorption | Methylene blue | Perlite | Rate constants | Thermodynamic activation parameters
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı JOURNAL OF HAZARDOUS MATERIALS
Dergi ISSN 0304-3894
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 06-2004
Cilt No 109
Sayı 1
Sayfalar 141 / 148
Doi Numarası 10.1016/j.jhazmat.2004.03.003
Makale Linki http://linkinghub.elsevier.com/retrieve/pii/S0304389404001451