Yazarlar |
Sedat Ondaral
Karadeniz Teknik Üniversitesi, Türkiye |
Elif Celik
|
Orcun Caglar Kurtuluş
|
Doç. Dr. Elif AŞIKUZUN TOKEŞER
Kastamonu Üniversitesi, Türkiye |
Ismail Yakın
|
Özet |
The chitosan adsorption on films prepared using nanofibrillated cellulose (NFC) with different content of aldehyde group was studied by means of Quartz Crystal Microbalance with Dissipation (QCM-D). Results showed that frequency change (Δf) was higher when the chitosan adsorbed on NFC film consisting more aldehyde group indicating the higher adsorption. The (Δf) and dissipation (ΔD) factors completely changed during adsorption of chitosan pre-treated with acetic acid: Δf increased and ΔD decreased, oppositely to un-treated chitosan adsorption. After acid treatment, molecular weight and crystallinity index of chitosan decreased addition to change in chemical structure. It was found that more phosphate buffered saline (PBS), as a model liquid for wound exudate, adsorbed to acid treated chitosan-NFC film, especially to film having more aldehyde groups. Comparing with bare NFC film, chitosan-NFC films adsorbed less PBS because chitosan crosslinked the NFC network and blocked the functional groups of NFC and thus, preventing swelling film. |
Anahtar Kelimeler |
Aldehyde content | Chitosan | Nanofibrillated cellulose | PBS | QCM-D |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | Carbohydrate Polymers |
Dergi ISSN | 0144-8617 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Makale Dili | İngilizce |
Basım Tarihi | 04-2018 |
Cilt No | 186 |
Sayı | 1 |
Sayfalar | 192 / 199 |
Doi Numarası | 10.1016/j.carbpol.2017.12.028 |