New N,N'-bis(thioamido)thiocarbohydrazones and carbohydrazones: synthesis, structure characterization, antioxidant activity, corrosion inhibitors and DFT studies
Yazarlar (5)
Prof. Dr. Muhammet Serdar ÇAVUŞ Kastamonu Üniversitesi, Türkiye
Doç. Dr. Hasan Yakan Ondokuz Mayis Üniversitesi, Türkiye
Dr. Öğr. Üyesi Cihan ÖZORAK Kastamonu Üniversitesi, Türkiye
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
Prof. Dr. Temel Kan BAKIR Kastamonu Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Research on Chemical Intermediates (Q3) | ||
| Dergi ISSN | 0922-6168 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 01-2022 |
| Cilt / Sayı / Sayfa | 48 / 4 / 1593–1613 | DOI | 10.1007/s11164-022-04659-z |
| Makale Linki | http://dx.doi.org/10.1007/s11164-022-04659-z | ||
| UAK Araştırma Alanları |
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| Özet |
| New symmetric N,N'-bis(thioamido)thio/carbohydrazones (1–4) were prepared from thio/carbohydrazide and various isothiocyanates with high yields and characterized the structures of the compounds. The compounds were evaluated as new corrosion inhibitors for corrosion of mild steel in 0.1 M HCl solutions using polarization and electrochemical impedance spectroscopy (EIS) techniques, and all compounds showed effective inhibitory properties. Antioxidant activity values determined using the DPPH method for all compounds showed higher antioxidant activity than the standard Trolox (5.89 µM). The IC50 values of the compounds were obtained between 3.45 and 4.25 µM, and also showed a ranking of , with antioxidant activities better than Trolox. Compound 4 (1,5-bis((3-fluorophenyl)carbamothioyl)carbonohydrazide) exhibited the highest activity in terms of both antioxidant and anti … |
| Anahtar Kelimeler |
| Antioxidant | Carbothioamides | Corrosion inhibitor | DFT analysis | Spectroscopic elucidation |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 20 |
| Google Scholar | 20 |