Yazarlar |
Sıtkı Aktaş
Giresun Üniversitesi, Türkiye |
Fatih Ünal
Giresun Üniversitesi, Türkiye |
Mustafa Şükrü Kurt
Türkiye |
Mümin Mehmet Koç
Türkiye |
Tayfun Arslan
Türkiye |
Prof. Dr. Mahmut GÜR
Kastamonu Üniversitesi, Türkiye |
Burhan Coşkun
Türkiye |
Zöhre Görünmez Güngör
Türkiye |
Özet |
A peripherally tetrachalcone substituted copper(II) phthalocyanine was achieved by cyclotetramerization of the phthalonitrile in the presence of anhydrous CuCl2. The modified CuPc was thermally coated on WOx thin films from which a In/WOx/CuPc/In heterojunction was obtained. The surface of the thin films was investigated using scanning electron microscopy (SEM), where energy dispersive X-ray spectra (EDX) was used to confirm chemical structure. The crystal structures of the thin films were characterized using X-ray diffractometry (XRD). To determine the photovoltaic properties of the heterojunction, I–V plots were obtained under dark and various levels of illumination. It was seen that the heterojunction was responsive to the external light. Using the I–V plots, different diode parameters such as ideality factor, barrier height, series resistance, etc., were calculated. These plots also revealed that the In/WOx/CuPc/In heterojunction exhibits negative differential resistance (NDR) characteristics. Photodiode characteristics indicate that the heterojunction exhibits self-powered photodiode behaviours. It was seen that In/WOx/CuPc/In heterojunctions are sensitive to the external light that photovoltaic characteristics alter when the light intensity alters. However, no clear relation between the light intensity and photovoltaic characteristics were evidenced. |
Anahtar Kelimeler |
Copper phthalocyanine | I–V characteristics | Negative differential resistance | Photovoltaic properties | Phthalocyanine |
Makale Türü | Özgün Makale |
Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
Dergi Adı | Elsevier BV |
Dergi ISSN | 0925-3467 |
Dergi Tarandığı Indeksler | SCI-Expanded |
Dergi Grubu | Q1 |
Makale Dili | Türkçe |
Basım Tarihi | 04-2023 |
Cilt No | 138 |
Sayı | 1 |
Sayfalar | 113709 / 113809 |
Doi Numarası | 10.1016/j.optmat.2023.113709 |
Makale Linki | http://dx.doi.org/10.1016/j.optmat.2023.113709 |