| Yazarlar |
Serkan Demir
Giresun Üniversitesi, Türkiye |
|
Prof. Dr. Mahmut GÜR
Kastamonu Üniversitesi, Türkiye |
Prof. Dr. Nesrin ŞENER
Kastamonu Üniversitesi, Türkiye |
Prof. Dr. İzzet ŞENER
Kastamonu Üniversitesi, Türkiye |
|
Gökhan Alpaslan
Giresun Üniversitesi, Türkiye |
| Özet |
| A new thiadiazole ligand, N-ethyl-5- (benzo[b]thien-2-yl-)-1,3,4-thiadiazol-2-amine (BTH), was prepared from 3-methyl-1-benzofuran-2-carboxylic acid and N-ethylhydrazinecarbothioamide precursors. Corresponding silver(I) complex, tetrakis(N-ethyl-5-(benzo[b]thien-2-yl-)-1,3,4-thiadiazol-2-amine)silver(I) nitrate [Ag2(BTH)4](NO3)2 (1), was prepared. The structures of BTH and 1 were characterized by 1H-NMR, 13C-NMR, FT-IR, elemental analysis and HR-MS techniques. Furthermore, molecular structure of 1 was illuminated by X-ray crystallography. Owing to strong anagsotic interaction, crystal structure of the complex revealed an intriguing asymmetric monomer unit even with two same ligands in 2:1 metal-to-ligand stoichiometry. Photoluminescence properties of the complex were investigated by solid and solution media emission measurements. Excited and emissive state behavior of the complex was further analyzed by quantum chemical TD-DFT calculations and natural transition orbital (NTO) analyses. |
| Anahtar Kelimeler |
| 1,3,4-Thiadiazole ligands | anagostic interaction | excited state calculations | photophysical properties | silver(I) complex |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Journal of Coordination Chemistry |
| Dergi ISSN | 0095-8972 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q3 |
| Makale Dili | İngilizce |
| Basım Tarihi | 09-2019 |
| Cilt No | 72 |
| Sayı | 18 |
| Sayfalar | 3071 / 3087 |
| Doi Numarası | 10.1080/00958972.2019.1685089 |
| Makale Linki | https://www.tandfonline.com/doi/full/10.1080/00958972.2019.1685089 |
