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Synthesis, Characterization, and Theoretical Calculation of New Azo Dyes Derived from [1,5‐ ]Pyrimidine‐5‐one Having Solvatochromic Properties      
Yazarlar
Prof. Dr. Nesrin ŞENER Prof. Dr. Nesrin ŞENER
Kastamonu Üniversitesi, Türkiye
Prof. Dr. Mahmut GÜR Prof. Dr. Mahmut GÜR
Kastamonu Üniversitesi, Türkiye
Doç. Dr. Muhammet Serdar ÇAVUŞ Doç. Dr. Muhammet Serdar ÇAVUŞ
Kastamonu Üniversitesi, Türkiye
Öğr. Gör. Dr. Merve ZURNACI Öğr. Gör. Dr. Merve ZURNACI
Kastamonu Üniversitesi, Türkiye
Prof. Dr. İzzet ŞENER Prof. Dr. İzzet ŞENER
Kastamonu Üniversitesi, Türkiye
Özet
7-Amino-3-phenylazo-2-methyl-4H-pyrazolo[1,5-a]pyrimidine-5-one (3) was synthesized by the reaction of 5-amino-3-methyl-4-phenylazo-1H-pyrazole and 2-aminobenzothiazole with ethyl cyanoacetate in acetic acid at 150°C. Four novel heterocyclic azo disperse dyes were obtained by the coupling of heterocyclic amines-based diazonium chloride with compound 3. They were purified and characterized by elemental analysis, FTIR, and 1 H NMR. Furthermore, solvatochromic behaviors of related dyes were studied in detail by using ultraviolet–visible absorption spectrometer. The experimental data were supported by density functional theory using b3lyp/cc-pvtz level calculations, and a detailed analysis of predicted tautomeric structures was made.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Journal of Heterocyclic Chemistry
Dergi ISSN 0022-152X
Dergi Tarandığı Indeksler SCI
Dergi Grubu Q3
Makale Dili İngilizce
Basım Tarihi 01-2019
Cilt No 56
Sayı 3
Sayfalar 1101 / 1110
Doi Numarası 10.1002/jhet.3497
Makale Linki https://onlinelibrary.wiley.com/doi/abs/10.1002/jhet.3497