Investigation of two o -hydroxy Schiff bases in terms of prototropy and radical scavenging activity
Yazarlar (6)
Çiğdem Albayrak Kaştaş Sinop Üniversitesi, Türkiye
Prof. Dr. Gökhan Kaştaş Samsun Üniversitesi, Türkiye
Prof. Dr. Aytaç Güder Giresun Üniversitesi, Türkiye
Prof. Dr. Mahmut GÜR Kastamonu Üniversitesi, Türkiye
Prof. Dr. Halit MUĞLU Kastamonu Üniversitesi, Türkiye
Orhan Büyükgüngör
Ondokuz Mayıs Üniversitesi, Türkiye
Ondokuz Mayıs Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Molecular Structure | ||
| Dergi ISSN | 0022-2860 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 02-2017 |
| Cilt / Sayı / Sayfa | 1130 / 1 / 623–632 | DOI | 10.1016/j.molstruc.2016.11.023 |
| Makale Linki | https://linkinghub.elsevier.com/retrieve/pii/S0022286016311784 | ||
| UAK Araştırma Alanları |
Organik Kimya
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| Özet |
| Two Schiff bases, namely (E)-4,6-dibromo-3-methoxy-2-[(phenylimino)methyl]phenol (1) and (Z)-2,4-dibromo-6-[(4-buthylphenylamino)methylene]-5-methoxycyclohexa-2,4-dienone (2), have been investigated by considering solvent, substituent and temperature dependence of prototropy, and scavenging activities. Experimental (X-ray diffraction, UV–vis and NMR) and computational (DFT) techniques have been used to obtain key data on prototropy and other properties of interest. X-ray and UV–vis results underline the variability in the structural preferences of the compounds with respect to the phase and solvent media conditions. This kind of tautomeric behavior has been elaborated by 1H NMR and 13C NMR experiments performed at room and low temperatures. Radical scavenging properties of two compounds have been probed for their usage potentials as therapeutic agent and ingredient in medicinal and … |
| Anahtar Kelimeler |
| Keto-amine | NMR | Phenol-imine | Scavenging activity | Schiff base | Tautomerism | X-ray |
Science Direct
Investigation of two o -hydroxy Schiff bases in terms of prototropy and radical scavenging activity
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 20 |
| Google Scholar | 29 |