New AB3-type porphyrins with piperidine and morpholine motifs; synthesis and photo-physicochemical and biological properties
Yazarlar (6)
Kevser Harmandar
Gebze Teknik Üniversitesi, Türkiye
Gebze Teknik Üniversitesi, Türkiye
Dr. Öğr. Üyesi Gülay GİRAY Kastamonu Üniversitesi, Türkiye
Dr. Öğr. Üyesi Emel Önal Doğuş Üniversitesi, Türkiye
İbrahim F. Sengül Gebze Teknik Üniversitesi, Türkiye
Prof. Dr. Sadin Özdemir Mersin Üniversitesi, Türkiye
Prof. Dr. Devrim Atilla Gebze Teknik Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Dalton Transactions (Q1) | ||
| Dergi ISSN | 1477-9226 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2023 |
| Cilt / Sayı / Sayfa | 52 / 9 / 2672–2683 | DOI | 10.1039/d2dt03738f |
| Makale Linki | rsc.li/dalton | ||
| Özet |
| In this study, new unsymmetrical meso-tetraaryl AB3-type porphyrins 1 and 2 were successfully synthesized by the reaction of p-bromobenzaldehyde and p-hydroxybenzaldehyde with pyrrole in propionic acid. AB3-type porphyrin building blocks with hydroxyl functionality (1 and 2) were further used to generate both covalently linked metal free and Zn(II) porphyrins 3–6 having piperidine and morpholine heterocyclic units. These novel compounds were characterized by using 1H NMR, 13C NMR, FT-IR and MALDI-TOF spectrophotometry. The photophysical and photochemical properties of compounds 1–6 were investigated by employing UV–vis absorption and fluorescence emission spectroscopy in tetrahydrofuran (THF). From the view of biological properties, the antioxidant capacities of porphyrins were determined by using DPPH radical scavenging activity and 2 was determined as the most potent porphyrin … |
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BM Sürdürülebilir Kalkınma Amaçları
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| Scopus | 1 |
| Google Scholar | 1 |