Solvatochromism and Optoelectronic Properties of Thiosemicarbazone Derivatives Having π-Conjugated Systems
Yazarlar (4)
Yunus Emre Kara Bitlis Eren Üniversitesi, Türkiye
Yadigar Gülseven Sıdır Bitlis Eren Üniversitesi, Türkiye
İsa Sıdır Bitlis Eren Üniversitesi, Türkiye
Prof. Dr. Fatma Kandemirli Kastamonu Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Journal of Solution Chemistry (Q4) | ||
| Dergi ISSN | 0095-9782 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | Scopus | ||
| Makale Dili | Türkçe | Basım Tarihi | 02-2023 |
| Cilt / Sayı / Sayfa | 52 / 5 / 570–587 | DOI | 10.1007/s10953-023-01248-5 |
| Makale Linki | http://dx.doi.org/10.1007/s10953-023-01248-5 | ||
| UAK Araştırma Alanları |
Teorik Kimya
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| Özet |
| The electronic structures, solvatochromism, and LSER (Linear Solvation Energy Relationship) properties of thiosemicarbazone derivatives having five different π-conjuged systems have been investigated. UV–Vis absorption spectra of TSC (Thiosemicarbazone) derivatives have been measured in 18 solvent media with different polarities. The global electronic transition in these compounds is described as π−π* electronic transition resulting from the resonance in the thiosemicarbazone group. The other lower wavelength maxima are denoted to the π−π* electronic transition in the indole ring and the n−π* electronic transition in the carboxyl group. To determine as analytical solvent–solute interactions of global electronic transitions has been studied with using LSERs with using Kamlet–Taft and Catalán parameters. The solvatochromic models between electronic transition wavenumbers with Reichardt parameter … |
| Anahtar Kelimeler |
| Bandgap | Catalán | Electronic structure | Electronic transitions | Kamlet–Taft | LSER | Optoelectronic | Solvatochromism | Thiosemicarbazone |
| Atıf Sayıları | |
| Scopus | 3 |
| Google Scholar | 3 |