| Yazarlar (4) |
Murat Saraçoğlu
Erciyes Üniversitesi, Türkiye |
Prof. Dr. Fatma KANDEMİRLİ
Kastamonu Üniversitesi, Türkiye |
|
Ayhan Özalp
|
|
Zülbiye Kökbudak
Erciyes Üniversitesi, Türkiye |
| Özet |
| The 2,4-dioxopentanoic acid derivatives (3d-f) were obtained from the reaction of 4-acetyl-5-(1-naphthyl)furan-2,3dione (1) with various nitrogenous nucleophiles (2d-f). The structures of these newly synthesized compounds (3d-f) were determined from the FT-IR, 1H and 13C NMR spectroscopic data and elemental analyses. In addition to experimental analysis, quantum-chemical calculations of derivatives of 2,4dioxopentanoic acid (3d-f) were carried out by using B3LYP method with basis set of the 6-311G(d,p) in order to find molecular properties. Quantum chemical features such as HOMO, LUMO, HOMO-LUMO energy gap, chemical hardness, chemical softness, electronegativity, chemical potential, dipole moment etc. were calculated and discussed |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | Uluslararası alan indekslerindeki dergilerde yayınlanan tam makale |
| Dergi Adı | International Journal of Science and Engineering Investigations |
| Dergi ISSN | 2251-8843 |
| Dergi Tarandığı Indeksler | Index Copernicus |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2017 |
| Cilt No | 6 |
| Sayı | 60 |
| Sayfalar | 50 / 57 |
