| Yazarlar (6) |
Özalp Ayhan
|
|
Zülbiye Kökbudak
|
|
Saracoğlu Murat
|
Prof. Dr. Fatma KANDEMİRLİ
Kastamonu Üniversitesi, Türkiye |
|
Ilhan Özer
|
|
Can Vurdu
|
| Özet |
| The 1-amino-5-benzoyl-4-phenyl-1H-pyrimidine-2-one/-thione (1a-b) were synthesized with the reaction of 4-benzoyl-5-phenyl-2, 3-furandione and acetophenonsemicarbazone/-thiosemicarbazone. The study was extended to reactions of the compounds (1a-b) with acide chlorides (2a-d). Thus, some new pyrimidine derivatives (3a-h) were synthesized. The novel 2-oxopyrimidin-1 (2H)-yl-amides derivatives were characterized by elemental analysis, IR, 1H and 13C NMR spectral data. All of them were evaluated according to their previous analogues. In addition to experimental analysis, quantum-mechanical calculations for derivatives of 2-oxopyrimidin-1 (2H)-yl-amides were performed by using B3LYP method with the 6-311G (d, p), 6-311++ G (2d, 2p) basis sets in order to find molecular properties. As a result, both frontier orbital energies for the containing-sulphur molecules were found low while these energies were high for the containingoxygen molecules. |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Chemical Science Review and Letters |
| Dergi ISSN | 2278-6783 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 04-2015 |
| Cilt No | 4 |
| Sayı | 14 |
| Sayfalar | 719 / 728 |
