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Experimental and theoretical studies on some new pyrrol 2 3 diones formation     
Yazarlar
İsmail Yıldırım
Erciyes Üniversitesi, Türkiye
Prof. Dr. Fatma KANDEMİRLİ Prof. Dr. Fatma KANDEMİRLİ
Kocaeli Üniversitesi, Türkiye
Özet
4-Benzoyl-5-phenyl-2,3-furandione (1) reacts with asymmetric disubstituted urea derivatives like 1,1-dimethylurea (2n) and 1,1-dielhylurea (2b) by the elimination of a H2O molecule to give the 4-benzoyl-1-(N, N-dialkylcarbamyl)-5-phenyl-2,3-pyrroldiones 3a and 3b. The structures of 3a,b were determined by the 13C NMR, 1H NMR, IR spectroscopic data and elemental analyses. The electronic structures of the reactants, their transition states, intermediate states, and final products of the reactions were investigated on the basis of AM 1 and ab initio (DFT) methods. © 2003 Wiley Periodicals, Inc.
Anahtar Kelimeler
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı HETEROATOM CHEMISTRY
Dergi ISSN 1042-7163
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 01-2004
Cilt No 15
Sayı 1
Sayfalar 9 / 14
Doi Numarası 10.1002/hc.10204
Makale Linki http://doi.wiley.com/10.1002/hc.10204