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Sarioz Ozlem
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Kandemirli Fatma
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Oznergiz Sena
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| Özet |
| Functionalized bis(amino)phosphines of the type PhP(NR2) 2 have been synthesized by treating PhPCl2 with 4-methylpiperidine or 4-benzylpiperidine. The ligands react with aqueous hydrogen peroxide, elemental sulfur or selenium to give the corresponding chalcogenides in good yield. The molybdenum complexes of the bis(amino)phosphines have been obtained. All of the compounds were obtained in good yields and were characterized by IR, NMR and elemental analysis. Quantum chemical calculations, such as HOMO-LUMO energies, Mulliken charges etc., were carried out using B3LYP/6-31G(d,p), a version of the DFT method with the standard gaussian 09 software package program for the bis(amino)phosphines and their chalcogenides. The experimental and theoretical results show that PPh(NC5H9CH3)2 (1) and PPh(NC 5H9CH2C6H5)2 (2) are strong σ-donors and have similar electronic properties. © 2013 Elsevier Ltd. All rights reserved. |
| Anahtar Kelimeler |
| Aminophosphine chalcogenides | Aminophosphine complexes | Aminophosphines | DFT | Quantum chemical calculations |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Polyhedron |
| Dergi ISSN | 0277-5387 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2014 |
| Cilt No | 68 |
| Sayfalar | 103 / 111 |
| Doi Numarası | 10.1016/j.poly.2013.08.048 |
| Makale Linki | http://linkinghub.elsevier.com/retrieve/pii/S0277538713006116 |
| Atıf Sayıları | |
| SCOPUS | 4 |
