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Inhibition Performance and Adsorptive Behavior of Three Amino Acids on Cold Rolled Steel in 1 0 M HCl Chemical Electrochemical and Morphological Studies    
Yazarlar
Amin Ma
Hazzazi Oa
Prof. Dr. Fatma KANDEMİRLİ
Kastamonu Üniversitesi, Türkiye
M Saracoglu
Özet
Three selected amino acids, namely, serine (Ser), threonine (Thr), and glutamine (Glu), were tested as corrosion inhibitors for cold-rolled steel (CRS) in 1.0 M hydrochloric acid (HCl) solutions at different temperatures (283 K to 333 K). Chemical (weight loss) and electrochemical (Tafel polarization) methods were used in this study. Electrochemical frequency modulation (EFM), a non-destructive corrosion measurement technique that can directly give values of corrosion current without prior knowledge of Tafel constants, was also used. Experimental corrosion rates determined by the Tafel extrapolation method were compared with those obtained using the EFM technique and the weight-loss method. Morphologies of the corroded and the inhibited surfaces were studied by means of atomic force microscopy (AFM) and scanning electron microscopy (SEM). Tafel plots showed that the three tested amino acids act as mixed-type inhibitors. The three tested amino acids appeared to function through adsorption following the Temkin adsorption isotherm model. Glu was found to inhibit corrosion of steel more effectively than Ser and Thr. © 2012, NACE International.
Anahtar Kelimeler
adsorption,amino acids,cold-rolled steel,corrosion inhibition,hydrochloric acid solution,scanning electron microscopy
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Corrosion
Dergi ISSN 0010-9312
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 08-2012
Cilt No 68
Sayı 8
Sayfalar 688 / 698
Doi Numarası 10.5006/0506
Makale Linki http://corrosionjournal.org/doi/abs/10.5006/0506