Effect of fiber modification with carboxymethyl celluloseon the efficiency of a microparticle flocculation system
Yazarlar (3)
Sedat Ondaral
Dr. Öğr. Üyesi Orçun Çağlar KURTULUŞ
Mustafa Usta
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Chemical Papers
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 09-2010
Cilt / Sayı / Sayfa 65 / 1 / 16–22 DOI 10.2478/s11696-010-0090-y
UAK Araştırma Alanları
Lif ve Kağıt Teknolojisi
Özet
AbstractCarboxymethyl cellulose (CMC) has been used widely to enhance dry strength of paper and uniformity of sheet in the papermaking industry. Besides these positive effects, it may affect the fines retention and dewatering processes negatively. These negative effects are mainly seen when fiber modifications with high CMC dosages are studied in laboratory scale. In this paper, the effect of fiber modification with CMC on the deposition of precipitated calcium carbonate (PCC) and on the dewatering process in the presence of cationic polyacrylamide (CPAM)/bentonite microparticle flocculation system is examined. It was determined that fiber modification with 10 mg g−1 of CMC decreased PCC deposition at the initial addition of CPAM and gave better PCC deposition at 2 mg g−1 of CPAM. It was also observed that PCC deposition on unmodified fibers is higher at lower CPAM concentration. PCC deposition was found as almost stable after a maximum value obtained at 0.5 mg g−1 of bentonite concentration for fiber modified with 40 mg g−1 of CMC. This indicates that interaction between CPAM and bentonite particles changed due to higher surface charge and CMC conformation on fibers. Results of the dewatering experiments showed that CMC modification increased the drainage time due to a denser and more plugged sheet. This negative effect was compensated with higher concentrations of CPAM and bentonite. On the other hand, dewatering is also affected by the mass ratio of CMC and CPAM, which was not the optimum one in this study at lower of CPAM. Thus, the increase in the drainage time in the presence of CMC on the fiber surface could be also caused by incorrect ratios of chemicals because the effect of CMC on the drainage time was not observed at higher concentrations of CPAM.
Anahtar Kelimeler
BM Sürdürülebilir Kalkınma Amaçları
Atıf Sayıları
Effect of fiber modification with carboxymethyl celluloseon the efficiency of a microparticle flocculation system

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İletişim
  • Kastamonu Üniversitesi Rektörlüğü, Kuzeykent Kampüsü, Merkez/Kastamonu
  • unis@kastamonu.edu.tr 03662801000
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