| Yazarlar |
Majid Monajjemi
Islamic Azad University, Central Tehran Branch, Iran |
|
Yaser Rafiee
Islamic Azad University, Central Tehran Branch, Iran |
|
Fatemeh Mollaamin
Kastamonu University, Turkey |
|
Sara Shahriari
Islamic Azad University, Central Tehran Branch, Iran |
| Özet |
| Abstract: Several ions of (Formula presented.) rings in viewpoint of diatropic situation (aromatic) and also paratropic position (anti-aromatic) have been studied. By this work, it has been exhibited that some of these ion rings presented planar and some others exhibit a quasi-planar structures, due to Jahn--Teller and pseudo Jahn--Teller effects. Via this effort, we demonstrated that the global aromaticity or global anti-aromaticity can be assigned on the 4n + 2 (or 4n) electron counting rule for either π- or σ-electrons in the planar structures. In addition, the structures of these ions have been discussed computationally and confirmed via comparisons of experimental photoelectron spectrophotometry. |
| Anahtar Kelimeler |
| aromaticity | B clusters n | Jahn--Teller effect | pseudo‑Jahn--Teller effect |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
| Dergi Adı | Russian Journal of Physical Chemistry A |
| Dergi ISSN | 0036-0244 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2023 |
| Cilt No | 97 |
| Sayı | 1 |
| Sayfalar | 151 / 167 |
| Doi Numarası | 10.1134/S0036024423010223 |
| Atıf Sayıları |
