| Yazarlar |
Arş. Gör. Hatice Bike ULU
Kastamonu Üniversitesi, Türkiye |
Doç. Dr. Nejdet DEĞERMENCİ
Kastamonu Üniversitesi, Türkiye |
|
Filiz Bengü Dilek
Orta Doğu Teknik Üniversitesi, Türkiye |
| Özet |
| Chloridazon (CLZ), also named as Pyrazon and classified as organochlorine pesticides, is widely used during sugar beets cultivation. CLZ being a pesticide with high solubility in water is likely to end up in surface and groundwater bodies because of its high mobility in soil. Due to its toxic properties, it may cause serious problems in human health and ecological cycle. In the present study, the removal of CLZ pesticide by Fenton and photo-Fenton processes was investi-gated. The effects of parameters such as H2 O2, Fe(II), initial CLZ concentration, pH, and temperature were studied. It was observed that CLZ completely disappeared within 1 h and 20 min by the Fenton and photo-Fenton process, respectively, under optimal conditions. The optimal conditions for each processes were attained as 7.5 mg/L Fe(II), 50 mg/L H2 O2, 40 mg/L initial CLZ, pH 3 and 20°C for Fenton process, and 5 mg/L Fe2+, 50 mg/L H2 O2, 60 mg/L initial CLZ, pH 3 and 20°C for photo-Fenton process. The reaction kinetics of CLZ followed Behnajady–Modirdhahla–Ghanbery kinetic model. Desphenyl CLZ, pyridazine-3,4,5-trione, oxaluric acid, and 5-hydroxyhydantion were identified as CLZ degradation by-products. Accordingly, the degradation pathway was proposed. |
| Anahtar Kelimeler |
| Chloridazon removal,Fenton,Photo-Fenton,Kinetics,By-products |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | DESALINATION AND WATER TREATMENT |
| Dergi ISSN | 1944-3994 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2020 |
| Cilt No | 194 |
| Doi Numarası | 10.5004/dwt.2020.25905 |
| Makale Linki | http://dx.doi.org/10.5004/dwt.2020.25905 |
| Atıf Sayıları | |
| WoS | 4 |
| SCOPUS | 2 |
