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Decolorization of reactive azo dye from aqueous solutions with Fenton oxidation process: effect of system parameters and kinetic study    
Yazarlar
Doç. Dr. Nejdet DEĞERMENCİ
Kastamonu Üniversitesi, Türkiye
Dr. Öğr. Üyesi Gökçe Didar DEĞERMENCİ
Kastamonu Üniversitesi, Türkiye
Arş. Gör. Hatice Bike ULU
Türkiye
Özet
The decolorization of Drimaren Orange HF 2GL (DOHF) reactive azo dye from aqueous solutions with the Fenton oxidation process was researched. With the aim of determining optimum conditions, the effects of different operating parameters such as H2 O2, Fe(II), chloride ion and initial DOHF concentration, initial pH and solution temperature on the decolorization were investigated. Optimum conditions were determined as 30°C temperature, pH 3, 300 mg/L DOHF, 15 mg/L Fe(II) and 100 mg/L H2 O2 . The presence of chloride ion had a negative effect on the decolorization, while the increase in reaction temperature caused an increase in the decolorization. Using experimental data, the decolorization kinetics for dye molecules was investigated and the best kinetic model representing experimental data was found to be the Behnajady–Modirshahla–Ghanbary (BMG) kinetic model. Additionally, Fourier transform infrared spectroscopy analysis was performed before and after Fenton oxidation to show degradation of dye molecules.
Anahtar Kelimeler
Oxidation,Kinetics,Decolorization,IR spectroscopy
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Desalination and Water Treatment
Dergi ISSN 1944-3994
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce
Basım Tarihi 02-2019
Cilt No 169
Sayfalar 363 / 371
Doi Numarası 10.5004/dwt.2019.24672
Makale Linki http://www.deswater.com/DWT_abstracts/vol_169/169_2019_363.pdf