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Improvement of Corrosion Resistance for Brass in 3.5% NaCl Media by Using 4-fluorophenyl-2,5-dithiohydrazodicarbonamide     
Yazarlar
Mothana Ghazi Kadhim Alfalah
Kastamonu University, Turkey
Ahmed Elid
Kastamonu University, Turkey
Amgad Ahmed Abdo Ali
Kastamonu University, Turkey
Arş. Gör. Dr. Ersin KAMBERLİ Arş. Gör. Dr. Ersin KAMBERLİ
Kastamonu Üniversitesi, Türkiye
Arş. Gör. Bahar NAZLI Arş. Gör. Bahar NAZLI
Kastamonu Üniversitesi, Türkiye
Sevilay Koyun
Kastamonu University, Turkey
Alihan Tosun
Kastamonu University, Turkey
Muhammed Kadirlioğlu
Kastamonu University, Turkey
Fatma Elkassum
Kastamonu University, Turkey
Saleh Quddus Saleh
Kastamonu University, Turkey
Abdulrahman Obied
Kastamonu University, Turkey
Prof. Dr. Fatma KANDEMİRLİ Prof. Dr. Fatma KANDEMİRLİ
Kastamonu Üniversitesi, Türkiye
Özet
Corrosion poses a significant challenge for numerous industries. The use of corrosion inhibitors is essential within these industries. The efficacy of environmentally friendly corrosion inhibitors should remain high even when used at low concentrations. In the present study, the compound 4-fluorophenyl-2,5-dithiohydrazodicarbonamide (FTSC) was used as a corrosion inhibitor for brass in 3.5% NaCl solution. The inhibitor efficiency was determined by using a series of electrochemical techniques such as open circuit potential (OCP), potential dynamic polarisation (PDP), linear polarisation resistance (LPR), and electrochemical impedance spectroscopy (EIS). All experimental tests have been done in stagnant conditions. The findings of the experiments revealed that the compound FTSC looked to be of the cathodic type. Furthermore, the maximum inhibitor efficiency was reached at 98.28% at 1 × 10-3 and at an immersion time of 1 h. The current density was reduced from 16.5 to 0.284 mA.cm-2. The adsorption of compound on the brass surface in 3.5% NaCl solution obeyed the Langmuir isotherm with a low negative value of the standard Gibbs free energy of adsorption (-33.8 kJ/mol ΔGads (chemisorption and physisorption). The results confirmed that the compound FTSC can be used as a corrosion inhibitor for brass in 3.5% NaCl.
Anahtar Kelimeler
Brass | Corrosion Inhibition | Electrochemistry
Makale Türü Özgün Makale
Makale Alt Türü SCOPUS dergilerinde yayımlanan tam makale
Dergi Adı Journal of the Turkish Chemical Society, Section A: Chemistry
Dergi ISSN 2149-0120
Makale Dili İngilizce
Basım Tarihi 01-2023
Cilt No 10
Sayı 4
Sayfalar 869 / 876
Doi Numarası 10.18596/jotcsa.1268115