Yazarlar |
Mothana Ghazi Kadhim Alfalah
Kastamonu University, Turkey |
Ahmed Elid
Kastamonu University, Turkey |
Amgad Ahmed Abdo Ali
Kastamonu University, Turkey |
Arş. Gör. Dr. Ersin KAMBERLİ
Kastamonu Üniversitesi, Türkiye |
Arş. Gör. Bahar NAZLI
Kastamonu Üniversitesi, Türkiye |
Sevilay Koyun
Kastamonu University, Turkey |
Alihan Tosun
Kastamonu University, Turkey |
Muhammed Kadirlioğlu
Kastamonu University, Turkey |
Fatma Elkassum
Kastamonu University, Turkey |
Saleh Quddus Saleh
Kastamonu University, Turkey |
Abdulrahman Obied
Kastamonu University, Turkey |
Prof. Dr. Fatma KANDEMİRLİ
Kastamonu Üniversitesi, Türkiye |
Özet |
Corrosion poses a significant challenge for numerous industries. The use of corrosion inhibitors is essential within these industries. The efficacy of environmentally friendly corrosion inhibitors should remain high even when used at low concentrations. In the present study, the compound 4-fluorophenyl-2,5-dithiohydrazodicarbonamide (FTSC) was used as a corrosion inhibitor for brass in 3.5% NaCl solution. The inhibitor efficiency was determined by using a series of electrochemical techniques such as open circuit potential (OCP), potential dynamic polarisation (PDP), linear polarisation resistance (LPR), and electrochemical impedance spectroscopy (EIS). All experimental tests have been done in stagnant conditions. The findings of the experiments revealed that the compound FTSC looked to be of the cathodic type. Furthermore, the maximum inhibitor efficiency was reached at 98.28% at 1 × 10-3 and at an immersion time of 1 h. The current density was reduced from 16.5 to 0.284 mA.cm-2. The adsorption of compound on the brass surface in 3.5% NaCl solution obeyed the Langmuir isotherm with a low negative value of the standard Gibbs free energy of adsorption (-33.8 kJ/mol ΔGads (chemisorption and physisorption). The results confirmed that the compound FTSC can be used as a corrosion inhibitor for brass in 3.5% NaCl. |
Anahtar Kelimeler |
Brass | Corrosion Inhibition | Electrochemistry |
Makale Türü | Özgün Makale |
Makale Alt Türü | SCOPUS dergilerinde yayımlanan tam makale |
Dergi Adı | Journal of the Turkish Chemical Society, Section A: Chemistry |
Dergi ISSN | 2149-0120 |
Makale Dili | İngilizce |
Basım Tarihi | 01-2023 |
Cilt No | 10 |
Sayı | 4 |
Sayfalar | 869 / 876 |
Doi Numarası | 10.18596/jotcsa.1268115 |