Synthesis and Characterization of Polymer Particles as Metal‐Free Catalysts for Electrooxidation and Methanolysis of Sodium Borohydride
Yazarlar (7)
Doç. Dr. Kutalmış GÖKKUŞ Kastamonu Üniversitesi, Türkiye
Doç. Dr. Sefika Kaya Eskişehir Osmangazi Üniversitesi, Türkiye
Doç. Dr. Derya Yildiz Eskişehir Osmangazi Üniversitesi, Türkiye
Ceren Saka
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Mahmut GÜR Kastamonu Üniversitesi, Türkiye
Prof. Dr. Vural Bütün Eskişehir Osmangazi Üniversitesi, Türkiye
Hilal Kivrak
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Chemistryselect (Q3) | ||
| Dergi ISSN | 2365-6549 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SCI-Expanded | ||
| Makale Dili | Türkçe | Basım Tarihi | 07-2024 |
| Cilt / Sayı / Sayfa | 9 / 26 / 202304975–202304987 | DOI | 10.1002/slct.202304975 |
| Makale Linki | https://doi.org/10.1002/slct.202304975 | ||
| UAK Araştırma Alanları |
Organik Kimya
Spektroskopi
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| Özet |
| In this study, trimethylolpropane triglycidyl ether/diethylenetriamine (TD) and glutaraldehyde/diethylenetriamine (GD) polymer particles are synthesized as catalysts for hydrogen production from NaBH4 methanolysis and NaBH4 electrooxidation. SEM, FT‐IR and TGA characterization methods are applied to determine the surface morphologies, chemical structures, thermal stability and decomposition of the synthesized polymer particles. The parameters affecting the hydrogen generation rate on NaBH4 methanolysis are investigated and optimum conditions are determined. Under optimum conditions, the hydrogen generation rates of TD and GD polymer particles are obtained as 34903.2 and 97998 mL/min.gcat, respectively. The activation energies of TD and GD polymer particles are also calculated as 16.86 and 18.14 kJ/mol, respectively. The catalytic activities of polymer particles as anode catalysts in NaBH4 … |
| Anahtar Kelimeler |
| Electrooxidation | Hydrogen production | Methanolysis | Polymer particles | Sodium borohydride |
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Scopus | 9 |
| Google Scholar | 9 |