| Yazarlar |
Faramarz Kazemı
|
Dr. Öğr. Üyesi Farzin ARİANPOUR
Kastamonu Üniversitesi, Türkiye |
|
Hamıd Reza Rezaie
|
| Özet |
| In this research, formation mechanism and kinetics of vacuum carbothermal synthesis of zirconium carbide using zirconium acetate and sucrose are discussed. The study of non-isothermal reduction was conducted by thermogravimetry analysis and heating the samples in argon and vacuum conditions up to 1773 K, and then the heat exchange values of reactions were calculated. Isothermal formation mechanism of carbide phase was investigated by heating the samples at 1473 K and 1673 K in argon and vacuum atmospheres followed by X-ray diffraction and quantitative phase analysis. Results showed that in non-isothermal state, the carbothermal reduction of zirconia is a heterogeneous reaction with multiple steps. For isothermal reaction, the kinetic parameters such as activation energy and pre-exponential factor were calculated as 70.56 kJ mol−1 and 11.22 × 10−2 S−1, respectively. It was presented that the activation energy value extracted from isothermal reaction is completely in accordance with the final step of non-isothermal results. |
| Anahtar Kelimeler |
| Carbothermal reduction | Kinetics | Thermal analysis | Vacuum | Zirconium carbide |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY |
| Dergi ISSN | 1388-6150 |
| Dergi Tarandığı Indeksler | SCI-Expanded |
| Dergi Grubu | Q4 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2020 |
| Cilt No | 139 |
| Sayı | 1 |
| Sayfalar | 67 / 73 |
| Doi Numarası | 10.1007/s10973-019-08368-5 |
| Makale Linki | http://link.springer.com/10.1007/s10973-019-08368-5 |
| Atıf Sayıları | |
| SCOPUS | 4 |
| Google Scholar | 6 |
