Processing, phase evaluation and mechanical properties of MoSi2 doped 4TaC-HfC based UHTCs consolidated by spark plasma sintering
Yazarlar (6)
Dr. Öğr. Üyesi Farzin ARİANPOUR Kastamonu Üniversitesi, Türkiye
Farhad Golestanifard Iran University Of Science And Technology, İran
Hamıd Reza Rezaie Iran University Of Science And Technology, İran
Mehdı Mazaheri National Institute For Materials Science, Japonya
Doç. Dr. Ali Çelik Bilecik Şeyh Edebali Üniversitesi, Türkiye
Ferhat Kara Anadolu Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Journal of Refractory Metals and Hard Materials (Q4)
Dergi ISSN 0263-4368 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI
Makale Dili İngilizce Basım Tarihi 01-2016
Cilt / Sayı / Sayfa 56 / 1 / 1–7 DOI 10.1016/j.ijrmhm.2015.11.011
Özet
In this research, binary 4TaC–HfC based composites were consolidated using carbide materials and addition of 0–15 vol.% MoSi2 by means of spark plasma sintering at 2000 °C. The nearly full dense and monophase specimens were fabricated with a relative density value higher than 99%. Mechanical tests revealed values of 18–19 GPa and 4–4.3 MPa·m1/2, for average Vickers hardness and fracture toughness of the composites, respectively. Analysis of linear shrinkage during densification revealed that MoSi2 addition increased densification rate and decreased the time required to reach full density at 2000 °C. It is proposed that at the intermediate stage of sintering, mass transfer can be accelerated by formation of a silicide based liquid phase and viscous flow mechanisms. The formation of binary 4TaC–HfC solid solution phase enhanced the densification process at the final stage of sintering.
Anahtar Kelimeler
Densification | Microstructure | Phase evolution | Spark plasma sintering | Tantalum hafnium carbide