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Identification of Marker Molecules in Aqueous Plant Extracts Affecting the Gold Nanostructures’ Morphology and Size        
Yazarlar
Mareia Ahmed-M Elgaleidh
Hafize Dilek Tepe
Türkiye
Fatma Doyuk
Türkiye
Prof. Dr. Talip ÇETER Prof. Dr. Talip ÇETER
Kastamonu Üniversitesi, Türkiye
Doç. Dr. İdris YAZGAN Doç. Dr. İdris YAZGAN
Türkiye
Özet
This work was performed as a comparative study using nine different aqueous pollen grain extracts from eight different genera (Juniperus, Biota, Cupressus, Abies, Pinus, Cedrus, Populus and Corylus) to synthesize gold nanostructures (AuNSs) to understand if there is any possible marker that helps to predict the final morphology and size of the AuNSs. Principal component analysis (PCA) revealed that Apigenin and Pinoresinol compounds are the marker molecules in determination of the AuNSs physical characteristics while total protein, reducing carbohydrate, flavonoid and phenol contents did not show any statistically meaningful outcome. The “dominancy hypothesis” was tested by paying attention to the most concentrated phenolic acids and flavonoids in the control of AuNSs morphology and size, for which correlation analysis were performed. The statistical findings were tested using two new more pollen extracts to validate the models. Three main findings of the study were (i) determination of Apigenin and Pinoresinol levels in pollen extract can give an insight into the AuNSs physical characters, (ii) the most concentrated phenolic acids and flavonoids don't need to be same to pose same dictative effect on AuNSs morphology and size, rather relatively abundant ones in the extract play the key role and (iii) differences in the polymeric structures (e. g. lignin, cellulosic compounds etc.) have minor effect on the final morphology and size of the AuNSs.
Anahtar Kelimeler
chemical composition | Gold nanostructure | pollen grain extract | statistical analysis
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı CHEMISTRY & BIODIVERSITY
Dergi ISSN 1612-1872
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q3
Makale Dili Türkçe
Basım Tarihi 02-2024
Cilt No 21
Sayı 2
Doi Numarası 10.1002/cbdv.202301349
Makale Linki http://dx.doi.org/10.1002/cbdv.202301349