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Preparation and Characterization of Pyridin-2-amine Functionalized Thiadiazole-Embedded Polymer Inclusion Membrane and Utilization of Its Heavy Metal Transport Efficiency      
Yazarlar
Mithat Çiçek
Giresun Üniversitesi, Türkiye
Seydahmet Çay
Giresun Üniversitesi, Türkiye
Mehmet Soner Engin
Giresun Üniversitesi, Türkiye
Prof. Dr. Nesrin ŞENER
Kastamonu Üniversitesi, Türkiye
Aiman Emhemad Omeran Aldwib
Doç. Dr. Mahmut GÜR
Kastamonu Üniversitesi, Türkiye
Özet
Abstract: 3-[5-(Cycloheximino)-4,5-dihydro-1,3,4-thiadiazol-2-yl]pyridine-2-amine was synthesized and used to make a novel pyrazole derivative embedded polymer inclusion membrane (Py@PIM). The surface and structure morphology of Py@PIM was detected using thermogravimetric analysis, FT-IR spectroscopy and scanning electron microscopy. Donnan dialysis system was also used to assess the transport efficacy of Py@PIM towards 5 heavy metals (Co, Cd, Cu, Ni, Pb). The results show that according to the kinetic coefficient, the order is Pb > Ni > Co > Cd > Cu. Similar kinetic order was also observed in multiple cation experiments, in experiments where all cations were mixed in a single cell.
Anahtar Kelimeler
heavy metals | polymer inclusion membrane | surface characterization | thiadiazole
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Dergi ISSN 1070-3632
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q4
Makale Dili Türkçe
Basım Tarihi 08-2024
Cilt No 94
Sayı 8
Sayfalar 2038 / 2043
Doi Numarası 10.1134/S1070363224080176
Makale Linki http://dx.doi.org/10.1134/s1070363224080176