Preparation and Characterization of Pyridin-2-amine Functionalized Thiadiazole-Embedded Polymer Inclusion Membrane and Utilization of Its Heavy Metal Transport Efficiency
Yazarlar (6)
M. Cicek
Giresun Üniversitesi, Türkiye
S. Cay
Giresun Üniversitesi, Türkiye
M. S. Engin
Giresun Üniversitesi, Türkiye
Prof. Dr. Nesrin ŞENER Kastamonu Üniversitesi, Türkiye
A. E.O. Aldwib
Kastamonu Üniversitesi, Türkiye
Prof. Dr. Mahmut GÜR Kastamonu Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Russian Journal of General Chemistry
Dergi ISSN 1070-3632 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili Türkçe Basım Tarihi 08-2024
Cilt / Sayı / Sayfa 94 / 8 / 2038–2043 DOI 10.1134/S1070363224080176
Makale Linki http://dx.doi.org/10.1134/s1070363224080176
UAK Araştırma Alanları
Organik Kimya Spektroskopi
Özet
3-[5-(Cycloheximino)-4,5-dihydro-1,3,4-thiadiazol-2-yl]pyridine-2-amine was synthesized and used to make a novel pyrazole derivative embedded polymer inclusion membrane (Py@PIM). The surface and structure morphology of Py@PIM was detected using thermogravimetric analysis, FT-IR spectroscopy and scanning electron microscopy. Donnan dialysis system was also used to assess the transport efficacy of Py@PIM towards 5 heavy metals (Co, Cd, Cu, Ni, Pb). The results show that according to the kinetic coefficient, the order is Pb > Ni > Co > Cd > Cu. Similar kinetic order was also observed in multiple cation experiments, in experiments where all cations were mixed in a single cell.
Anahtar Kelimeler
heavy metals | polymer inclusion membrane | surface characterization | thiadiazole