| Yazarlar |
Güneş Süheyla Kürkçüoğlu
Eskişehir Osmangazi Üniversitesi, Turkey |
|
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Turkey |
|
Okan Zafer Yeşilel
Eskişehir Osmangazi Üniversitesi, Turkey |
Dr. Öğr. Üyesi Kutalmış GÖKKUŞ
Kastamonu Üniversitesi, Türkiye |
|
Hakan Ünver
Eskisehir Technical University, Turkey |
|
Onur Şahin
Sinop University, United States |
| Özet |
| Two new heteronuclear Cd(II)/Co(III) compounds, {[Cd(1-meim)3Cd0.5(1-meim)Co(μ-CN)4(CN)2]}n (1) and {[Cd(1-etim)3Cd0.5(1-etim)2Co(μ-CN)3(CN)3]⋅H2O}n (2) (1-meim: 1-methylimidazole, 1-etim = 1-ethylimidazole), have been synthesized and characterized using elemental analysis, FT-IR and Raman spectroscopy, single-crystal X-ray diffraction techniques. The single crystal X-ray study shows that the compound 1 exhibited a 1D double chain structure and is further linked into 3D supramolecular architectures through C–H⋅⋅⋅N and π⋅⋅⋅π interactions. Whereas the compound 2 displayed 2D network which is extended into a 3D supramolecular framework by O–H⋅⋅⋅N hydrogen bonds and C–H∙∙∙π interactions. In 1 and 2, each Co(III) ion is coordinated by six carbon atoms from cyanide ligands, thus showing an octahedral coordination geometry. Cd1 and Cd2 ions exhibited two different geometries, distorted trigonal bipyramidal and octahedral. Furthermore, phase purities, catalytic and thermal properties were investigated. |
| Anahtar Kelimeler |
| 1-Ethylimidazole complex | 1-Methylimidazole complex | Cadmium(II) complex | Coordination polymer | Hexacyanocobaltate(III) complex | Hydrogen production | Thymol oxidation |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale |
| Dergi Adı | Inorganica Chimica Acta |
| Dergi ISSN | 0020-1693 |
| Dergi Grubu | Q2 |
| Makale Dili | İngilizce |
| Basım Tarihi | 01-2025 |
| Cilt No | 574 |
| Sayı | 1 |
| Doi Numarası | 10.1016/j.ica.2024.122400 |
| Atıf Sayıları |
