Heteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and catalytic activities
Yazarlar (6)
Prof. Dr. Güneş Süheyla Kürkçüoğlu Eskişehir Osmangazi Üniversitesi, Türkiye
Seray Kekeç
Eskişehir Osmangazi Üniversitesi, Türkiye
Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Okan Zafer Yeşilel Eskişehir Osmangazi Üniversitesi, Türkiye
Doç. Dr. Kutalmış GÖKKUŞ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Hakan Ünver Eskisehir Technical University, Türkiye
Onur Şahin Sinop University, Türkiye
| Makale Türü | Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale) | ||
| Dergi Adı | Inorganica Chimica Acta (Q2) | ||
| Dergi ISSN | 0020-1693 Wos Dergi Scopus Dergi | ||
| Dergi Tarandığı Indeksler | SSCI | ||
| Makale Dili | İngilizce | Basım Tarihi | 01-2025 |
| Cilt / Sayı / Sayfa | 574 / 1 / 122400–0 | DOI | 10.1016/j.ica.2024.122400 |
| Makale Linki | https://doi.org/10.1016/j.ica.2024.122400 | ||
| UAK Araştırma Alanları |
Hava Kirliliği ve Kontrolü
Temiz Üretim Teknolojileri
Su Kirliliği ve Kontrolü
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| Özet |
| Two new heteronuclear Cd(II)/Co(III) compounds, {[Cd(1-meim)3Cd0.5(1-meim)Co(μ-CN)4(CN)2]}n (1) and {[Cd(1-etim)3Cd0.5(1-etim)2Co(μ-CN)3(CN)3]⋅H2O}n (2) (1-meim: 1-methylimidazole, 1-etim = 1-ethylimidazole), have been synthesized and characterized using elemental analysis, FT-IR and Raman spectroscopy, single-crystal X-ray diffraction techniques. The single crystal X-ray study shows that the compound 1 exhibited a 1D double chain structure and is further linked into 3D supramolecular architectures through Csingle bondH⋅⋅⋅N and π⋅⋅⋅π interactions. Whereas the compound 2 displayed 2D network which is extended into a 3D supramolecular framework by Osingle bondH⋅⋅⋅N hydrogen bonds and Csingle bondH∙∙∙π interactions. In 1 and 2, each Co(III) ion is coordinated by six carbon atoms from cyanide ligands, thus showing an octahedral coordination geometry. Cd1 and Cd2 ions … |
| Anahtar Kelimeler |
| 1-Ethylimidazole complex | 1-Methylimidazole complex | Cadmium(II) complex | Coordination polymer | Hexacyanocobaltate(III) complex | Hydrogen production | Thymol oxidation |
Science Direct
Heteronuclear cadmium(II)/cobalt(III) cyanide coordination polymers with 1-methylimidazole and 1-ethylimidazole ligands: synthesis, characterization and catalytic activities
BM Sürdürülebilir Kalkınma Amaçları
| Atıf Sayıları | |
| Web of Science | 2 |
| Scopus | 2 |
| Google Scholar | 3 |