Hyperbranched novel functional polymeric catalysts offering new approaches in hydrogen production via NaBH4 methanolysis
Yazarlar (5)
Doç. Dr. Kutalmış GÖKKUŞ Kastamonu Üniversitesi, Türkiye
Arş. Gör. Aysegul Ozbal Eskişehir Osmangazi Üniversitesi, Türkiye
Prof. Dr. Mahmut GÜR Kastamonu Üniversitesi, Türkiye
S. Alper Akalin
Dokuz Eylül Üniversitesi, Türkiye
Vural Bütün Eskişehir Osmangazi Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı International Journal of Hydrogen Energy (Q1)
Dergi ISSN 0360-3199 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 01-2025
Cilt / Sayı / Sayfa 98 / 1 / 106–126 DOI 10.1016/j.ijhydene.2024.12.059
Makale Linki https://doi.org/10.1016/j.ijhydene.2024.12.059
UAK Araştırma Alanları
Hava Kirliliği ve Kontrolü Temiz Üretim Teknolojileri Su Kirliliği ve Kontrolü
Özet
Hydrogen energy is one of the best alternative energy sources for the future. However, there are still difficulties in its production, storage and transportation. This study focused extensively on the hydrogen production via methanolysis of NaBH4. There are two main objectives of this study. First, to reveal the catalytic effects of different functional groups on hydrogen production. Second, to reveal the high performance of polyaramids in hydrogen production. This was achieved by the synthesis and application of three different polyaramid derivative polymers containing amide, amide-ether and amide-sulfone. The polymers were characterized by FT-IR, SEM, BET, TGA and XPS analyzes. The amounts of catalyst (10–50 mg) and NaBH4 (25–175 mg) and various temperatures (0–60 °C) were optimized. The highest hydrogen production rate (HGR) was found 11857 mL H2.min−1gcat−1. In addition, within in the scope of …
Anahtar Kelimeler
Catalytic mechanisms | Hydrogen production | Methanolysis of NaBH4 | Polyaramid catalysts | Renewable energy