Electrochromic properties of tetrabutylammonium perchlorate-doped polypyrrole/ nanocellulose composite films
Yazarlar (10)
Sabina Jusufovic Istanbul Üniversitesi, Türkiye
Gizem Yıldırım Baştemur Istanbul Üniversitesi, Türkiye
Dilek Evecan İstanbul Teknik Üniversitesi, Türkiye
Prof. Dr. Sabriye Perçin Özkorucuklu Istanbul Üniversitesi, Türkiye
Esra Zayim İstanbul Teknik Üniversitesi, Türkiye
Göksenin Kalyon Istanbul Üniversitesi, Türkiye
Prof. Dr. Zeki Candan İstanbul Üniversitesi-Cerrahpaşa, Türkiye
Dr. Öğr. Üyesi Ekrem DURMAZ Kastamonu Üniversitesi, Türkiye
Prof. Dr. Ayhan Tozluoğlu Düzce Üniversitesi, Türkiye
Ayşe Erol Istanbul Üniversitesi, Türkiye
Makale Türü Özgün Makale (SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale)
Dergi Adı Thin Solid Films (Q3)
Dergi ISSN 0040-6090 Wos Dergi Scopus Dergi
Dergi Tarandığı Indeksler SCI-Expanded
Makale Dili İngilizce Basım Tarihi 02-2025
Cilt / Sayı / Sayfa 811 / 1 / 1–10 DOI 10.1016/j.tsf.2025.140606
Makale Linki https://www.sciencedirect.com/science/article/pii/S0040609025000070?casa_token=lP36MP0QA6YAAAAA:G_DIZTga1kNQuZ5jtBSqD49M1LU6sl7OtZo0Pzy0weNOzeAFNyEPYuNaIjhr7La2h_Ye0bLPpw
Özet
This study investigates electrochromic properties of tetrabutylammonium perchlorate (TBAP)-doped polypyrrole (PPy) and PPy/Nanocellulose (NC) composite films, where TBAP-doped PPy/NC composites were synthesized with various NC content ranging from 0 % to 100 % by volume in 0.1 M pyrrole solution and deposited on fluorine-doped tin oxide (FTO) glass using potentiostatic polymerization. The optimum polymerization time for depositing a uniform, adhesive and stable films on FTO with higher optical contrast between bleached and colored states are found to be 10 s at a constant voltage of 1.2 V. To compare the electrochromic properties of NC-free and NC-containing TBAP-doped PPy films, cyclic voltammetry (CV), chronoamperometry (CA), and optical transmittance spectroscopy were carried out in 0.1 M TBAP electrolyte. A reversible color change from yellow at – 0.6 V (bleached state) to blue gray at …
Anahtar Kelimeler
Cellulose | Conductive polymers | Electrochromic | Electrochromism | Electropolymerization | Nanocellulose | Polypyrrole | PPy