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Investigation of a novel Defatted Spent Coffee Ground (DSCG)-supported Ni catalyst for fuel cell and supercapacitor applications   
Yazarlar (10)
Tülin Avcı Hansu
Türkiye
R.R. Al-Samaraae
Doç. Dr. Muhammed Raşit ATELGE Doç. Dr. Muhammed Raşit ATELGE
Siirt Üniversitesi, Türkiye
Mustafa Kaya
Siirt Üniversitesi, Türkiye
Hilal Demir Kıvrak
Eskişehir Osmangazi Üniversitesi, Türkiye
İsmail Böğrekci
Türkiye
Yalçın Şevki Yıldız
Erciyes Üniversitesi, Türkiye
Selahaddin Orhan Akansu
Erciyes Üniversitesi, Türkiye
Sebahattin Ünalan
Erciyes Üniversitesi, Türkiye
Abdulazız Atabanı
Türkiye
Devamını Göster
Özet
With the increase in energy demand, a material that can be used in fuel cell applications has been developed for both energy storage and the use of alternative energy sources to fossil fuels. In this study, a new Defatted Spent Coffee Ground (DSCG)-based electrode material was synthesized for two different application areas. A new electrocatalyst synthesis was carried out by subjecting DSCG to chemical activation and carbonization processes. The glycerol electrooxidation performances of the catalysts synthesized at 10–50 % Ni loading rates were investigated by CV measurements. 30 % Ni-DSCG catalyst exhibited the highest catalytic activity with 3.290 mA/cm2.As a result of the electrochemical measurements, 30 % Ni-DSCG catalyst with the best catalytic performance was used as the supercapacitor electrode material. The electrochemical performances of the produced supercapacitor electrodes were tested at room temperature using galvanostatic charge-discharge (GCD), Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques, and the capacity and stability of the electrodes were calculated as a result of the findings. In the calculations, the energy and power density of the 30 % Ni-DSCG supercapacitor electrode were calculated as 22.897 Wh kg−1, 841.114 W kg−1, respectively. The supercapacitor electrode capacitance was found to be 50.48 F/g. Its cyclic capacity was found to be 90 %. It showed that the DSCG-based synthesized electrocatalyst could be a good option for energy storage technology as EDLC electrode material and fuel cell applications as anode catalyst due to its good conductivity, superior cyclic stability, environmental friendliness and low cost.
Anahtar Kelimeler
DSCG | Electrocatalyst | Electrooxidation | Supercapacitor
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Process Safety and Environmental Protection
Dergi ISSN 0957-5820
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q1
Makale Dili İngilizce
Basım Tarihi 11-2024
Cilt No 191
Sayı 1
Sayfalar 760 / 768
Doi Numarası 10.1016/j.psep.2024.08.093
Makale Linki http://dx.doi.org/10.1016/j.psep.2024.08.093