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Carbon molecular sieve production from defatted spent coffee ground using ZnCl2 and benzene for gas purification   
Yazarlar (8)
Mustafa Kaya
Türkiye
Doç. Dr. Muhammed Raşit ATELGE Doç. Dr. Muhammed Raşit ATELGE
Siirt Üniversitesi, Türkiye
Mesut Bekiroğulları
Siirt Üniversitesi, Türkiye
Cigdem Eskicioglu
Ae Atabani
Gopalakrishnan Kumar
Ys Yildiz
Sebahattin Ünalan
Erciyes Üniversitesi, Türkiye
Devamını Göster
Özet
The aim of the current study is to manufacture molecular sieve from the defatted spent coffee ground. The defatted spent coffee ground for the specified particle size (100 μm) was chemically activated with different agents (ZnCl2, H3PO4, KOH) and then carbonized at different temperatures (400–900 °C). A thorough characterization of the produced activated carbon was performed and activated carbons with the highest BET surface area were subsequently used to produce carbon molecular sieve. The surface modification was performed with benzene vapor at different temperatures (600–900 °C) and different combustion times (30–90 min.). In addition to the BET analysis, SEM, TGA and FT-IR analysis were also undertaken. The results obtained through characterizations showed that the pore diameters of carbon molecular sieve produced from defatted spent coffee ground varied from 2 to 4 Å. To conclude, the results suggest that the fabricated carbon molecular sieve can be used for the removal of impurities such as CH4, CO2, NOx and other impurities in natural and biogas considering the porosity of the sieves.
Anahtar Kelimeler
Benzene | Carbon molecular sieve (CMS) | Defatted spent coffee ground | Gas purification
Makale Türü Özgün Makale
Makale Alt Türü SSCI, AHCI, SCI, SCI-Exp dergilerinde yayımlanan tam makale
Dergi Adı Fuel
Dergi ISSN 0016-2361
Dergi Tarandığı Indeksler SCI-Expanded
Dergi Grubu Q1
Makale Dili İngilizce
Basım Tarihi 10-2020
Cilt No 277
Sayı 118183
Sayfalar 1 / 11
Doi Numarası 10.1016/j.fuel.2020.118183
Makale Linki https://linkinghub.elsevier.com/retrieve/pii/S0016236120311790