| Yazarlar (4) |
Büşra Çuhadar
|
|
Ayfer Kalkan Burat
|
|
Gülay Giray
|
|
Sadin Özdemir
|
| Özet |
| We report the preperation of dichlorophenylthio substituted phthalonitrile (2) and its novel non-peripherally tetra sübstituted metallo phthalocyanines {Zn (3), Cu (4) and Mn (5)}. Characterization of newly synthesized compounds was performed by common spectroscopic techniques such as NMR, IR, UV--Vis and mass spectroscopies. The biological properties of the novel non-peripherally dichlorophenylthio substituted Pcs (3--5) and peripherally substituted derivatives (6, 7) were examined for the first time. Comparison of the biological properties of non-peripheral (α- substitution) substituted Pcs with those of peripheral derivatives (β-substution) was made. Among the studied compounds, 3 displayed the highest antioxidant activity as 99.42% at 200 mg/L. DNA cleavage activity of Pcs was also examined and all compounds were found to have DNA cleavage ability. Both peripherally and non-peripherally substituted ... |
| Anahtar Kelimeler |
| Makale Türü | Özgün Makale |
| Makale Alt Türü | SSCI, AHCI, SCI, SCI-Exp dergilerinde yayınlanan tam makale |
| Dergi Adı | Polyhedron |
| Dergi ISSN | 0277-5387 Wos Dergi Scopus Dergi |
| Dergi Tarandığı Indeksler | 0277-5387 |
| Dergi Grubu | Q2 |
| Makale Dili | İngilizce |
| Basım Tarihi | 11-2023 |
| Cilt No | 244 |
| Sayfalar | 116593 / 0 |
