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Improvement of the corrosion behaviour of mild steel by deposition of Zn–Ni–Cu–Fe–Cd from an acetate sulphate bath   
Yazarlar (4)
Meryem Evecen
Türkiye
Mothana Ghaz Alfalah,
Murat Saraçoğlu
Erciyes Üniversitesi, Türkiye
Prof. Dr. Fatma KANDEMİRLİ Prof. Dr. Fatma KANDEMİRLİ
Kastamonu Üniversitesi, Türkiye
Devamını Göster
Özet
Zn–Ni–Cu–Fe–Cd quinary alloy was successfully electrodeposited on mild steel from acetate-sulphate baths with only cathodic potential applied during linear sweep voltammetry. The influence of scan rate (1 mV/s, 5 mV/s and 10 mV/s) as well as the effect of organic additives: 4-(4-nitrophenyl)-3-thiosemicarbazide or 4-(3-methoxyphenyl)--3-thiosemicarbazide, on the surface appearance and deposit composition were investigated. Three electrochemical techniques, potentiodynamic polarisation (PDP), linear polarisation resistance (LPR) and electrochemical impedance spectroscopy (EIS) were used to investigate the corrosion behaviour of the alloy composition after immersion in a solution containing 1 M HCl. Energy dispersive X-ray (EDX) and scanning electron microscopy (SEM) were carried out after deposition to provide a visual aspect of the coating. The lowest corrosion current density, the highest corrosion resistance, and the highest impedance were observed in ea ch alloy system at a scan rate of 1 mV/s. These values were: 67 µA/cm−2, 51 µA/cm−2, and 7.6 µA/cm−2 for PDP, 965 Ω · cm², 1117 Ω · cm², and 2853 Ω · cm² for LPR, and 1602 Ω · cm², 12938 Ω · cm², and 1595 Ω · cm² for EIS, corresponding to coatings without additives, coatings with the additive 4-(4-nitrophenyl)-3-thiosemicarbazide, and coatings with the additive 4-(3-methoxyphenyl)-3-thiosemicarbazide, respectively. From the SEM and EDX results it was concluded that 4-(3-methoxyphenyl)-3-thiosemicarbazide has a more pronounced effect on the coating than 4-(4-nitrophenyl)-3-thiosemicarbazide, probably due to its better adsorption on the surface of soft steel.
Anahtar Kelimeler
EIS | electrodeposition | organic additives | quinary alloy Zn–Ni–Cu–Fe–Cd | scan rate | SEM
Makale Türü Özgün Makale
Makale Alt Türü ESCI dergilerinde yayımlanan tam makale
Dergi Adı OCHRONA PRZED KOROZJĄ
Dergi ISSN 0473-7733
Dergi Tarandığı Indeksler scopus
Makale Dili Türkçe
Basım Tarihi 03-2025
Cilt No 1
Sayı 2
Sayfalar 41 / 47
Doi Numarası 10.15199/40.2025.2.2
Makale Linki https://doi.org/10.15199/40.2025.2.2